| 1107648-26-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• CAS: 1107648-26-9
• 化学式: C₂₁H₂₉NO*ClH
• 分子量: 347.928
• InChiKey: LLRFETJEGQINCR-BDQAORGHSA-N

反应信息

• 作为反应物：
  描述：

  在 sodium azide 、 三氟乙酸 作用下， 生成
  参考文献：
  名称：

  Chiral Tetraaminophosphonium Salt-Mediated Asymmetric Direct Henry Reaction

  摘要：

  Chiral tetraaminophosphonium salts 1 possessing the phosphorus-centered [5.5]-spirocyclic core have been designed and synthesized in a single step from L-valine-derived diamine. The three-dimensional molecular structure was successfully verified by the single-crystal X-ray diffraction analysis, which also identified a secondary interaction between the phosphonium cation and chloride ion via double hydrogen-bonding. The potential of this novel onium salt as a chiral organic molecular catalyst has been demonstrated in an application to asymmetric direct Henry reaction.

  DOI：

  10.1021/ja075152+
• 作为产物：
  描述：

  在 盐酸 作用下， 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of Chiral Tetraaminophosphonium Chlorides from N-Boc a-Amino Acid Esters

  摘要：

  DOI：

  10.3987/com-08-s(n)123