| 837365-22-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• CAS: 837365-22-7
• 化学式: C₁₂H₂₃O₃P
• 分子量: 246.287
• InChiKey: HTFTWIUFYDTRTK-HBNTYKKESA-N

物化性质

• 沸点：
  310.9±11.0 °C(Predicted)
• 密度：
  1.049±0.06 g/cm3(Predicted)

反应信息

• 作为反应物：
  描述：

  uranyl nirate hexahydrate 、 以 甲醇 为溶剂， 以100%的产率得到
  参考文献：
  名称：

  Uranyl nitrate complexes of camphene-derived organophosphorus ligands, and the X-ray crystal structure of [UO2(NO3)2(RPO3Me2)2] (R=endo-8-camphanyl)

  摘要：

  endo-8-Camphanylphosphinic acid [(2,2-dimethylbicyclo [2.2.1] hept-3-ylmethyl)phosphinic acid] camPO(2)H(2) 1 is readily oxidised to the corresponding phosphonic acid camPO(3)H(2) 2, the preferred reagent being SO2 in refluxing isopropanol. Methylation of the phosphonic acid 1 with diazomethane yields the methyl ester camPO(3)Me(2) 4. Oxidative chlorination of camPO(2)H(2) with SOCl2 produces the phosphonic dichloride camP(O)Cl-2 3, which gives the tertiary phosphine oxide camP(O)Ph2S on reaction with PhMgBr. The phosphonate ester 4 and phosphine oxide 5 readily form complexes 6 and 7 respectively with uranyl nitrate. The phosphonate complex 6 has been subjected to a single-crystal X-ray diffraction study. The structure determination was not straightforward, largely as a result of the combination of a dominant:scattering atom (uranium) and substantial disorder of the camphanyl groups. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00176-4