fac-(CO)3((p-tolyl)2P(CH2)2P(p-tolyl)2)MnH | 325781-69-9

• 英文名称: fac-(CO)3((p-tolyl)2P(CH2)2P(p-tolyl)2)MnH
• 英文别名: fac-(CO)3(dtpe)MnH
• CAS: 325781-69-9
• 化学式: C₃₃H₃₃MnO₃P₂
• 分子量: 594.509
• InChiKey: ISZNHJNHKLRLDA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(CO)3((p-tolyl)2P(CH2)2P(p-tolyl)2)Mn]2 、 正己醇 以 further solvent(s) 为溶剂， 以95%的产率得到fac-(CO)3((p-tolyl)2P(CH2)2P(p-tolyl)2)MnH
  参考文献：
  名称：

  Reactions of [(CO)3(P-P)Mn]2 with primary alcohols, where, P-P is dppe {Ph2P(CH2)2PPh2}, dppp {Ph2P(CH2)3PPh2}, dppb {Ph2P(CH2)4PPh2}, dpppe {Ph2P(CH2)5PPh2}, dtpe {(p-tol)2P(CH2)2P(p-tol)2}, or dcpe {(chex)2P(CH2)2P(chex)2}. Synthesis of fac-(CO)3(P-P)MnH and the X-ray structure of fac-(CO)3(dtpe)MnH

  摘要：

  Treatment of the manganese(tricarbonyl)diphosphine dimers [(CO)(3)(P-P)Mn](2) (where, P-P is dppe {Ph2P(CH2)(2)PPh2}, dppp {Ph2P(CH2)(3)PPh2}, dppb {Ph2P(CH2)(4)PPh2}, dpppe {Ph2P(CH2)(5)PPh2}, dtpe {(p-tol)(2)P(CH2)(2)P(p-tol)(2)}, and dcpe {((c)hex)(2)P(CH2)(2)P((c)hex)(2)}), with 1-propanol, 1-butanol, 1-pentanol, or 1-hexanol yielded fac-(CO)(3)(dppe)MnH (1), fac(CO)(3)(dppp)MnH (2), fac-(CO)(3)(dppb)MnH (3), fac-(CO)(3)(dpppe)MnH (4), fac-(CO)(3)(dtpe)MnH (5), and fac-(CO)(3)(dcpe)MnH (6), respectively, and the corresponding aldehydes. Also treatment of Mn-2(CO)(10) with P-P in 1-propanol, 1-butanol, 1-pentanol, or 1-hexanol yielded the corresponding manganese(I) hydrides (1-6) and aldehydes. Structural characterization of 5 demonstrates a manganese-hydrogen (Mn-H(1)) bond length of 1.57(3) Angstrom which is in close agreement with the manganese-hydrogen bond length of 1.60(2) Angstrom observed in (CO)(5)MnH by neutron diffraction analysis. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00473-3