13-Ethyl-13-aluminabicyclo[10.3.0]pentadec-1(12)-ene | 1257243-18-7

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 13-Ethyl-13-aluminabicyclo[10.3.0]pentadec-1(12)-ene
• 英文别名: 1-ethyl-2,3,4,5,6,7,8,9,10,11,12,13-dodecahydrocyclododeca[b]alumole
• CAS: 1257243-18-7
• 化学式: C₁₆H₂₉Al
• 分子量: 248.388
• InChiKey: RJHKMYIBGZJGMD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.31
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  13-Ethyl-13-aluminabicyclo[10.3.0]pentadec-1(12)-ene 在 1,2,3,4,5,6,7,8-八硫杂环辛烷 作用下， 以 甲苯 为溶剂， 反应 0.5h， 生成 13-phenyl-13-phosphabicyclo[10.3.0]pentadec-1(12)-ene 1-sulfide
  参考文献：
  名称：

  Targeted synthesis of 2,3-disubstituted 2-phospholenes using catalytic cycloalumination of acetylenes

  摘要：

  A preparative one-pot method for the synthesis of 2,3-dialkyl-substituted phosphol-2-enes by catalytic cycloalumination of symmetric acetylenes with AlEt3 catalyzed by Cp2ZrCl2 is developed. The reaction gives the corresponding aluminacyclopentenes, which then react in situ with phosphorus dihalides. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.05.029
• 作为产物：
  描述：

  环十二碳炔 、 三乙基铝 在 二氯二茂锆 作用下， 生成 13-Ethyl-13-aluminabicyclo[10.3.0]pentadec-1(12)-ene
  参考文献：
  名称：

  Targeted synthesis of 2,3-disubstituted 2-phospholenes using catalytic cycloalumination of acetylenes

  摘要：

  A preparative one-pot method for the synthesis of 2,3-dialkyl-substituted phosphol-2-enes by catalytic cycloalumination of symmetric acetylenes with AlEt3 catalyzed by Cp2ZrCl2 is developed. The reaction gives the corresponding aluminacyclopentenes, which then react in situ with phosphorus dihalides. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.05.029

文献信息

• Targeted synthesis of 2,3-disubstituted 2-phospholenes using catalytic cycloalumination of acetylenes
  作者：Vladimir A. D’yakonov、Alevtina L. Makhamatkhanova、Rina A. Agliullina、Tat’yana V. Tyumkina、Usein M. Dzhemilev

  DOI：10.1016/j.tetlet.2014.05.029

  日期：2014.7

  A preparative one-pot method for the synthesis of 2,3-dialkyl-substituted phosphol-2-enes by catalytic cycloalumination of symmetric acetylenes with AlEt3 catalyzed by Cp2ZrCl2 is developed. The reaction gives the corresponding aluminacyclopentenes, which then react in situ with phosphorus dihalides. (C) 2014 Elsevier Ltd. All rights reserved.