(E)-1-(dimethoxyphosphoryl)-3-m-tolylallyl dimethyl phosphate | 1408158-33-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂醇
• 英文名称: (E)-1-(dimethoxyphosphoryl)-3-m-tolylallyl dimethyl phosphate
• CAS: 1408158-33-7
• 化学式: C₁₄H₂₂O₇P₂
• 分子量: 364.272
• InChiKey: GYJNIMXUONLBKH-MDZDMXLPSA-N

反应信息

• 作为产物：
  描述：

  在 2-phenyl[1,3,2]dioxaborolane 、 水 、 potassium hydroxide 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以56%的产率得到(E)-1-(dimethoxyphosphoryl)-3-m-tolylallyl dimethyl phosphate
  参考文献：
  名称：

  Phenyldioxaborolane promoted synthesis of bisphosphine compounds

  摘要：

  Bisphosphine compounds have a wide range of applications. In this paper, we reported that bisphosphine compounds could be prepared in moderate to good yields from dialkyl acylphosphonates under mild conditions in the presence of phenyldioxaborolane and potassium hydroxide via a C-P bond cleavage and a subsequent 1,2-migration of phosphoryl group. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2012.09.088