[CuBr(2-acetylbenzimidazole phthalazin-1-ylhydrazone(-2H))] | 1269248-00-1

• 英文名称: [CuBr(2-acetylbenzimidazole phthalazin-1-ylhydrazone(-2H))]
• CAS: 1269248-00-1
• 化学式: C₁₇H₁₃BrCuN₆
• 分子量: 444.78
• InChiKey: YCJXOSFJGDDONO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-acetylbenzimidazole phthalazin-1-ylhydrazone 、 copper(ll) bromide 以 甲醇 为溶剂， 生成 [CuBr(2-acetylbenzimidazole phthalazin-1-ylhydrazone(-2H))]
  参考文献：
  名称：

  2-Acetylbenzimidazole phthalazin-1-ylhydrazone and its complexes with transition metals

  摘要：

  2-Acetylbenzimidazole phthalazin-1-ylhydrazone (H2L) and its complexes with Cu(II), Ni(II), Mn(II), Zn(II), Cd(II), and Fe(III) were synthesized. The structure of the complexes was determined on the basis of their elemental compositions, IR and ESR spectra, and thermogravimetric, conductometric, and magnetochemical studies. The dinuclear copper complex [CuL](2) was found to display strong antiferromagnetic exchange between the copper(II) ions. The ionization constants, energies of possible conformations of the hydrazone, geometric parameters of the dinuclear complex, and exchange parameters were calculated by quantum-chemical methods.

  DOI：

  10.1134/s1070363210120170