| 850427-62-2

• CAS: 850427-62-2
• 化学式: C₄₆H₃₇FeNO₂P₂
• 分子量: 753.6
• InChiKey: BQTLTPQKHWFGQL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-ethynyl-N-methyl-1,8-naphthalimide 、 ammonium hexafluorophosphate 、 [1,2-bis(diphenylphosphino)ethane](η5-cyclopentadienyl)iron(II) iodide 以 甲醇 为溶剂， 以10%的产率得到
  参考文献：
  名称：

  Group 8 and 10 metal acetylide naphthalimide dyads

  摘要：

  [M]-C&3bond; C-naphthalimide derivatives {[M] = CpNi(PPh3), CpFe(dppe), CpRu(dppe) and Cp*Ru(dppe)} have been prepared and their X-ray structures determined. The structures show significant non-linearity of the acetylide link, with concomitant v(C&3bond; C) at low energy and high intensity. Other properties confirm the strong-donor/strong-naphthalimide acceptor nature of the compounds. All the compounds exhibit an intense MLCT band in the visible spectrum that resolves into two bands in non-polar solvents. Spectroelectrochemistry of the CpFe species shows that the MLCT band disappears upon oxidation, and the appearance of a LMCT band at lower energy. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.12.013