p-cyneme-2-sulphonic acid S-benzylisothiouronium salt | 90254-06-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: p-cyneme-2-sulphonic acid S-benzylisothiouronium salt
• 英文别名: 5-isopropyl-2-methyl-benzenesulfonic acid ; S-benzyl-thiuronium-salt；5-Isopropyl-2-methyl-benzolsulfonsaeure; S-Benzyl-thiouronium-Salz
• CAS: 90254-06-1
• 化学式: C₈H₁₀N₂S*C₁₀H₁₄O₃S
• 分子量: 380.532
• InChiKey: CHDBIYUEZDRPEN-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  5-isopropyl-2-methyl-benzenesulfonic acid; sodium salt 、 S-benzylisothiouronium hydrochloride 以 水 为溶剂， 生成 p-cyneme-2-sulphonic acid S-benzylisothiouronium salt
  参考文献：
  名称：

  Mass spectral studies of alkylbenzenesulphonic acids through theirS-benzylisothiouronium salts

  摘要：

  AbstractThe mass spectra of alkylbenzenesulphonic acids in the form of their S‐benzylisothiouronium salts have been studied. These S‐benzylisothiouronium salts dissociated into two parent reactant ions: (i) alkylbenzenesulphonic acid and (ii) S‐benzylisothiourea. The characteristic fragmentation patterns of alkylbenzenesulphonic acids (0‐5 substituted alkyls) were studied and compared with those of the parent hydrocarbons. The intensity of the molecular ion peak decreased with the increase in the molecular weight of the sulphonic acids. Desulphonation as well as loss of the alkyl group was observed in all the spectra. Migration of the alkyl group from S to O, followed by degradation, was also observed in all the spectra studied.

  DOI：

  10.1002/oms.1210190109