1-benzyl-2-ethyl-4-phenylcyclobutan-1-ol | 131833-66-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 1-benzyl-2-ethyl-4-phenylcyclobutan-1-ol
• CAS: 131833-66-4
• 化学式: C₁₉H₂₂O
• 分子量: 266.383
• InChiKey: UJRYIMWQFRLRKP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.17
• 重原子数：
  20.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  20.23
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  α-butylbenzyl benzyl ketone 、 苯 、 甲醇 以8%的产率得到
  参考文献：
  名称：

  NAGESHWER, RAO B.;SYAMALA, M. S.;TURRO, N. J.;RAMAMURTHY, V., J. ORG. CHEM., 52,(1987) N 25, 5517-5521

  摘要：

  DOI：

文献信息

• Modification of photochemical reactivity by zeolites: Role of cations in controlling the behavior of radicals generated within faujasites
  作者：V. Ramamurthy、D.R. Corbin、D.F. Eaton、N.J. Turro

  DOI：10.1016/s0040-4039(01)93483-5

  日期：1989.1

  α-Alkyldibenzylketones included in cation exchanged faujasite type zeolites show photobehavior different from that in isotropic organic solvents. Rearrangement and disproportionation which do not contribute in solution are the major processes within the cavities of faujasites. Cation size plays a major role in controlling the pathway pursued by the primary and the secondary radical pair.

  阳离子交换八面沸石中包含的α-烷基二苄基酮的光行为不同于各向同性有机溶剂。在溶液中不起作用的重排和歧化是八面沸石腔内的主要过程。阳离子的大小在控制主要和次要自由基对所遵循的途径中起着重要作用。
• Modification of photochemical reactivity by zeolites. A comparison between zeolite-solvent slurry and dry solid photolyses
  作者：V. Ramamurthy、D. R. Corbin、N. J. Turro、Z. Zhang、M. A. Garcia Garibay

  DOI：10.1021/jo00001a048

  日期：1991.1

  The use of a zeolite-solvent slurry as a convenient medium to carry out photoreactions is illustrated with four examples, namely Norrish type I reaction of dibenzyl ketones, Norrish type I and type II reactions of alpha-alkylbenzyl benzyl ketones, Norrish type II reaction of aryl alkyl ketones, and photodimerization of acenaphthylene. Solvent present within the supercages of zeolites X and Y provides constraint on the mobility of the included guest molecules. Such restrictions are reflected in the product distributions. The difference in the product distribution obtained between the zeolite-solvent slurry and a homogeneous solution is often higher than that between the dry powder zeolites and a homogeneous solution.
• Modification of photochemical reactivity by zeolites. Norrish type I and type II reactions of ketones as photochemical probes of the interior of zeolites
  作者：V. Ramamurthy、D. R. Corbin、D. F. Eaton

  DOI：10.1021/jo00305a024

  日期：1990.8