5-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-enyl)(4-hydroxyphenyl)methyl]-10,10-dimethyl-7-(4-hydroxyphenyl)-10,11-dihydrobenzo[b][1,10]phenanthrolin-8(5H,7H,9H)-one | 1416441-14-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 5-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-enyl)(4-hydroxyphenyl)methyl]-10,10-dimethyl-7-(4-hydroxyphenyl)-10,11-dihydrobenzo[b][1,10]phenanthrolin-8(5H,7H,9H)-one
• CAS: 1416441-14-9
• 化学式: C₃₉H₃₈N₂O₅
• 分子量: 614.741
• InChiKey: STBYMZAEQBAZMG-UHFFFAOYSA-N

物化性质

• 熔点：
  263-264 °C
• 沸点：
  808.2±65.0 °C(Predicted)
• 密度：
  1.36±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

反应信息

• 作为产物：
  描述：

  8-氨基喹啉 、 对羟基苯甲醛 、 5,5-二甲基-1,3-环己二酮 以72%的产率得到5-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-enyl)(4-hydroxyphenyl)methyl]-10,10-dimethyl-7-(4-hydroxyphenyl)-10,11-dihydrobenzo[b][1,10]phenanthrolin-8(5H,7H,9H)-one
  参考文献：
  名称：

  Synthesis of hydrobenzo[b]phenanthrolinone derivatives proceeding from 8-aminoquinoline, and their spectral and luminescent properties

  摘要：

  By a three-component condensation of 8-aminoquinoline, aromatic aldehydes, and 1,3-diketones accompanied by the Hofmann-Martius rearrangement hydrobenzophenanthroline derivatives were synthesized. Their spectral and luminescence properties in ethanol solution were investigated at 293 and 77 K.

  DOI：

  10.1134/s1070428012110061