diacetatobis(4-methylmorpholine)palladium(II) | 919763-68-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: diacetatobis(4-methylmorpholine)palladium(II)
• CAS: 919763-68-1
• 化学式: C₁₄H₂₈N₂O₆Pd
• 分子量: 426.806
• InChiKey: WIAWECZSNQHJPM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  、 silver(I) acetate 以 四氢呋喃 为溶剂， 以50%的产率得到diacetatobis(4-methylmorpholine)palladium(II)
  参考文献：
  名称：

  Palladium acetate complexes with morpholine and 4-methylmorpholine. The structure of Pd(C4H9ON)2(OAc)2 · 2H2O

  摘要：

  Methods for the synthesis of new palladium(II) acetate complexes [L2Pd(OCOCH3)(2)], where L is N-coordinated morpholine (C4H9ON) or 4-methylmorpholine (C5H11ON), have been developed. The structure of the complex (C4H9ON)(2)Pd(OAc)(2) center dot 2H(2)O (1) has been established by X-ray diffraction. The crystals of 1 are monoclinic (C12H26O8N2Pd, M = 434.76), space group P2(1)/c, a = 9.129(3) angstrom, b = 16.227(5)angstrom, c = 6.159(2)angstrom, V = 878.5(5)angstrom(3), Z = 2. The palladium atom has a square-planar environment with the trans arrangement of ligands. The complex (C5H11ON)(2)Pd(OAc)(2) (2) has a similar structure, according to spectroscopic data.

  DOI：

  10.1134/s0036023606040127