ethenyl 1,1-dimethallyl ether | 88738-99-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: ethenyl 1,1-dimethallyl ether
• 英文别名: 1,1-dimethylallyl vinyl ether；3-(Ethenyloxy)-3-methylbut-1-ene；3-ethenoxy-3-methylbut-1-ene
• CAS: 88738-99-2
• 化学式: C₇H₁₂O
• 分子量: 112.172
• InChiKey: VKSMYXVSDYUVIJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  ethenyl 1,1-dimethallyl ether 反应 1.5h， 以65%的产率得到4-异庚烯醛
  参考文献：
  名称：

  Cohalogenation of Alkenes in Ethylene Oxide: Efficient Methodology for the Preparation of Allyl Vinyl Ether Precursors of γ,δ-Unsaturated Aldehydes

  摘要：

  对卤素共氟化-脱卤化顺序作为从简单烯烃制备烯丙基乙烯醚的方法进行了研究。烯烃1a-k在-80°C下与溴或氯在环氧乙烷的存在下反应， regio-和立体选择性地形成高产率的β,β′-二卤醚2a-k。这些β,β′-二卤醚中有两个经过选择性单脱卤化处理，使用叔丁醇钾生成几乎定量的2-卤烷基乙烯醚。使用过量的碱可生成良好产率的烯丙基乙烯醚3a-k。后者的热重排将其转化为相应的γ,δ-不饱和醛4a-j。

  DOI：

  10.1055/s-1993-25872
• 作为产物：
  描述：

  2-bromoethyl 2-bromo-1,1-dimethylpropyl ether 在 potassium tert-butylate 作用下， 以 二甲基亚砜 为溶剂， 以75%的产率得到ethenyl 1,1-dimethallyl ether
  参考文献：
  名称：

  Cohalogenation of Alkenes in Ethylene Oxide: Efficient Methodology for the Preparation of Allyl Vinyl Ether Precursors of γ,δ-Unsaturated Aldehydes

  摘要：

  对卤素共氟化-脱卤化顺序作为从简单烯烃制备烯丙基乙烯醚的方法进行了研究。烯烃1a-k在-80°C下与溴或氯在环氧乙烷的存在下反应， regio-和立体选择性地形成高产率的β,β′-二卤醚2a-k。这些β,β′-二卤醚中有两个经过选择性单脱卤化处理，使用叔丁醇钾生成几乎定量的2-卤烷基乙烯醚。使用过量的碱可生成良好产率的烯丙基乙烯醚3a-k。后者的热重排将其转化为相应的γ,δ-不饱和醛4a-j。

  DOI：

  10.1055/s-1993-25872

文献信息

• Tandem Pd(II)-Catalyzed Vinyl Ether Exchange−Claisen Rearrangement as a Facile Approach to γ,δ-Unsaturated Aldehydes
  作者：Xudong Wei、Jon C. Lorenz、Suresh Kapadia、Anjan Saha、Nizar Haddad、Carl A. Busacca、Chris H. Senanayake

  DOI：10.1021/jo062548f

  日期：2007.5.1

  A sequential allyl vinyl ether formation−Claisen rearrangement process catalyzed by a palladium(II)−phenanthroline complex is reported. The effects of allylic alcohol structure, type of vinylating agent, and palladium catalysts are discussed. This method provides a convenient approach to γ,δ-unsaturated aldehydes under mild conditions that avoid the use of toxic Hg(II) catalysts. The new methodology

  报道了钯（II）-菲咯啉配合物催化的烯丙基乙烯基醚的顺序形成-克莱森重排过程。讨论了烯丙醇结构，乙烯基化剂类型和钯催化剂的影响。该方法提供了一种在温和条件下避免使用有毒的Hg（II）催化剂的γ，δ-不饱和醛的简便方法。新方法已经成功地在千克规模上得到了证明。
• Acrylic rubber, acrylic rubber composition and cured rubber article thereof
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0290131A2

  公开（公告）日：1988-11-09

  An acrylic rubber obtainable by copolymerizing a monomer mixture of: (A) 70 to 99.99% by weight of at least one compound selected from the group consisting of alkyl acrylates and alkoxyalkyl acrylates, (B) 0.01 to 10% by weight of at least one compound represented by the general formula: wherein R' is a hydrogen atom or a methyl group; X is a hydrogen atom, -COOR6 (R6 is an alkyl group having 1-10 carbon atoms or an alkoxyalkyl group having 2-14 carbon atoms), or R2, R3 and R4 are independently hydrogen atoms or groups having 1-10 carbon atoms whose carbon atom adjacent to C=C has no hydrogen; R5 is a group having 1-10 carbon atoms whose carbon atom adjacent to C = C has no hydrogen; Y is or and n is 1 or 0, and (C) 0-20% by weight of at least one compound selected from the group consisting of other unsaturated compounds of the vinyl type, vinylidene type and vinylene type, in the presence of a radical polymerization initiator. Said acrylic rubber, when crosslinked with a crosslinking agent, gives a cured article having good heat resistance and a good compression set property and accordingly suitable for use as a hose or a sealing material.

  一种丙烯酸橡胶，可通过共聚以下单体混合物获得： (A) 至少一种选自丙烯酸烷基酯和丙烯酸烷氧基烷基酯组的化合物，其重量占 70%至 99.99%、 (B) 0.01%至 10%（按重量计）的至少一种由通式表示的化合物： 其中 R' 是氢原子或甲基；X 是氢原子、-COOR6（R6 是具有 1-10 个碳原子的烷基或具有 2-14 个碳原子的烷氧基烷基），或 R2、R3 和 R4 独立地是氢原子或具有 1-10 个碳原子且与 C=C 相邻的碳原子不含氢的基团；R5 是具有 1-10 个碳原子且与 C=C 相邻的碳原子不含氢的基团；Y 是 或 且 n 为 1 或 0，且 (C) 0-20% （按重量计）的至少一种选自乙烯基型、亚乙烯基型和亚乙烯基型其他不饱和 化合物的化合物，在有自由基聚合引发剂存在的情况下。所述丙烯酸橡胶与交联剂交联后，固化物具有良好的耐热性和良好的压缩永久变形性能，因此适合用作软管或密封材料。
• Thermoplastic elastomer composition, moldings using the same
  申请人：JSR Corporation

  公开号：EP1302507A2

  公开（公告）日：2003-04-16

  A thermoplastic elastomer composition having excellent heat aging characteristics, weather resistance, low-temperature physical properties, oil resistance and flexibility, and moldings using the same, such as hoses, are disclosed. The thermoplastic elastomer composition is obtained by dynamically heat treating a mixture containing (A) an olefin resin, (B) an unsaturated group-containing acrylic rubber, and (D) an inorganic filler in the presence of (E) a crosslinking agent, the component (B) comprising (B1) from 55 to 94.99% by weight of a structural unit derived from an acrylic acid alkyl ester monomer and/or an acrylic acid alkoxyalkyl ester monomer, (B2) from 0.01 to 20% by weight of a structural unit derived from a monomer having a carbon-carbon double bond in a side chain thereof, (B3) from 5 to 30% by weight of a structural unit derived from an unsaturated acrylonitrile monomer, and (B4) from 0 to 30% by weight of a structural unit derived from a monomer copolymerizable therewith, provided that the sum of (B1), (B2), (B3) and (B4) is 100% by weight.

  本发明公开了一种热塑性弹性体组合物，该组合物具有优异的热老化特性、耐候性、低温物理性能、耐油性和柔韧性，并公开了使用该组合物的模塑件，如软管。该热塑性弹性体组合物是通过动态热处理含有(A)烯烃树脂、(B)含不饱和基团的丙烯酸橡胶和(D)无机填料的混合物，在(E)交联剂的存在下获得的，组分(B)包括(B1)以重量计从丙烯酸烷基酯单体和/或丙烯酸烷氧基烷基酯单体衍生出的结构单元的 55% 至 94.99%，(B2)以重量计从丙烯酸烷基酯单体和/或丙烯酸烷氧基烷基酯单体衍生出的结构单元的 0.(B3)5-30%（按重量计）由不饱和丙烯腈单体衍生的结构单元，以及(B4)0-30%（按重量计）由可与之共聚的单体衍生的结构单元，条件是(B1)、(B2)、(B3)和(B4)之和为 100%（按重量计）。
• THERMOPLASTIC ELASTOMER COMPOSITION AND METHOD FOR PRODUCING SAME
  申请人：JSR Corporation

  公开号：EP1816163A1

  公开（公告）日：2007-08-08

  A thermoplastic elastomer composition obtained by dynamically heat-treating a mixture containing a thermoplastic resin (A) having a melting point of not less than 200°C and an elastomer (B) having a constitutional unit derived from an ester group-containing monomer in the presence of, as a crosslinking agent (C), a polymer (C-1) comprising a (meth)acrylate (c-1) unit having a weight average molecular weight (Mw) of 1,000 to 30,000 and a molecular weight distribution (Mw/Mn) of 1.0 to 4.0 and/or a polymer (C-2) which comprises 5 to 35 mass% of the (meth)acrylate (c-1) unit and 65 to 95 mass% of an aromatic vinyl monomer (c-2) unit, the polymer (C-2) having a weight average molecular weight (Mw) of 1,000 to 30,000 and a molecular weight distribution (Mw/Mn) of 1.0 to 4.0. The composition has a good sea-island structure as a whole and excellent cold resistance, and is useful as a substitute for acrylic rubbers.

  一种热塑性弹性体组合物，通过动态热处理含有熔点不低于 200°C 的热塑性树脂 (A) 和弹性体 (B) 的混合物而获得，弹性体 (B) 的结构单元来自含酯基的单体，作为交联剂 (C)，聚合物 (C-1) 包括(甲基)丙烯酸酯 (c-1)单元，其重量平均分子量 (Mw) 在 1,000 至 30,000 之间，分子量分布 (Mw/Mn) 在 1.0 至 4.0 之间，和/或聚合物 (C-2)，其包括 5 至 35 质量％的(甲基)丙烯酸酯 (c-1) 单元和 65 至 95 质量％的芳香族乙烯基单体 (c-1)。该聚合物（C-2）具有 1,000 至 30,000 的重量平均分子量（Mw）和 1.0 至 4.0 的分子量分布（Mw/Mn）。该组合物具有良好的整体海岛结构和优异的耐寒性，可用作丙烯酸橡胶的替代品。
• Oil-resistant thermoplastic elastomer composition and moldings using the same
  申请人：JSR CORPORATION

  公开号：US20030096071A1

  公开（公告）日：2003-05-22

  A thermoplastic elastomer composition having excellent heat aging characteristics, weather resistance, low-temperature physical properties, oil resistance and flexibility, and moldings using the same, such as hoses, are disclosed. The thermoplastic elastomer composition is obtained by dynamically heat treating a mixture containing (A) an olefin resin, (B) an unsaturated group-containing acrylic rubber, and (D) an inorganic filler in the presence of (E) a crosslinking agent, the component (B) comprising (B1) from 55 to 94.99% by weight of a structural unit derived from an acrylic acid alkyl ester monomer and/or an acrylic acid alkoxyalkyl ester monomer, (B2) from 0.01 to 20% by weight of a structural unit derived from a monomer having a carbon-carbon double bond in a side chain thereof, (B3) from 5 to 30% by weight of a structural unit derived from an unsaturated acrylonitrile monomer, and (B4) from 0 to 30% by weight of a structural unit derived from a monomer copolymerizable therewith, provided that the sum of (B1), (B2), (B3) and (B4) is 100% by weight.

  本发明公开了一种热塑性弹性体组合物，该组合物具有优异的热老化特性、耐候性、低温物理性能、耐油性和柔韧性，并公开了使用该组合物的模塑件，如软管。该热塑性弹性体组合物是通过动态热处理含有(A)烯烃树脂、(B)含不饱和基团的丙烯酸橡胶和(D)无机填料的混合物，在(E)交联剂的存在下获得的，组分(B)包括(B1)以重量计从丙烯酸烷基酯单体和/或丙烯酸烷氧基烷基酯单体衍生出的结构单元的 55% 至 94.99%，(B2)以重量计从丙烯酸烷基酯单体和/或丙烯酸烷氧基烷基酯单体衍生出的结构单元的 0.(B3)5-30%（按重量计）由不饱和丙烯腈单体衍生的结构单元，以及(B4)0-30%（按重量计）由可与之共聚的单体衍生的结构单元，条件是(B1)、(B2)、(B3)和(B4)之和为 100%（按重量计）。