[Pb(1,10-phenanthroline)(hexafluoroglutarate)](n) | 1217128-91-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [Pb(1,10-phenanthroline)(hexafluoroglutarate)](n)
• CAS: 1217128-91-0
• 化学式: C₁₇H₈F₆N₂O₄Pb
• 分子量: 625.452
• InChiKey: MFDHEAQKCHJQLI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pb(1,10-phenanthroline)(hexafluoroglutarate)](n) 以 neat (no solvent) 为溶剂， 生成 lead(II) oxide
  参考文献：
  名称：

  Synthesis, crystal structure and characterization of lead(II) coordination polymers with tetrafluorosuccinate/hexafluoroglutarate

  摘要：

  Two complexes, [Pb(TFSA)(wphen)](n) (1) and [Pb(HFGA)(phen)](n) (2) (TFSA=tetrafluorosuccinate, HFGA = hexafluoroglutarate, and phen = 1,10-phenanthroline) have been synthesized and structurally characterized by single-crystal X-ray diffraction. The 1 shows that the 2-D structure with six normal Pb-ligand bonds and one weak Pb center dot center dot center dot O bond, and then is further connected by C-H center dot center dot center dot O and C-H center dot center dot center dot F hydrogen bonds, forming a 3-D network. The 2 has 1-D structure with four normal Pb-ligand bonds that further produces a 3-D network by C-H center dot center dot center dot O, C-H center dot center dot center dot F hydrogen bonds, and weak Pb center dot center dot center dot O bonds. The two complexes display high thermal stability and luminescent properties. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2009.11.013
• 作为产物：
  描述：

  1,10-菲罗啉 、 lead(II) nitrate 、 六氟戊二酸 在 NaOH 作用下， 以 水 为溶剂， 以72%的产率得到[Pb(1,10-phenanthroline)(hexafluoroglutarate)](n)
  参考文献：
  名称：

  Synthesis, crystal structure and characterization of lead(II) coordination polymers with tetrafluorosuccinate/hexafluoroglutarate

  摘要：

  Two complexes, [Pb(TFSA)(wphen)](n) (1) and [Pb(HFGA)(phen)](n) (2) (TFSA=tetrafluorosuccinate, HFGA = hexafluoroglutarate, and phen = 1,10-phenanthroline) have been synthesized and structurally characterized by single-crystal X-ray diffraction. The 1 shows that the 2-D structure with six normal Pb-ligand bonds and one weak Pb center dot center dot center dot O bond, and then is further connected by C-H center dot center dot center dot O and C-H center dot center dot center dot F hydrogen bonds, forming a 3-D network. The 2 has 1-D structure with four normal Pb-ligand bonds that further produces a 3-D network by C-H center dot center dot center dot O, C-H center dot center dot center dot F hydrogen bonds, and weak Pb center dot center dot center dot O bonds. The two complexes display high thermal stability and luminescent properties. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2009.11.013