5,5-bis-(N-2-methyl-8-quinolylcarbamoyl)nonane | 135961-80-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 5,5-bis-(N-2-methyl-8-quinolylcarbamoyl)nonane
• 英文别名: 5,5-bis(N-2-methyl-8-quinolylcarbamoyl)nonane；2,2-dibutyl-N,N'-bis(2-methylquinolin-8-yl)propanediamide
• CAS: 135961-80-7
• 化学式: C₃₁H₃₆N₄O₂
• 分子量: 496.652
• InChiKey: AAIYOJLOTPWVHN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  37
• 可旋转键数：
  10
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  84
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  copper(II) acetate monohydrate 、 5,5-bis-(N-2-methyl-8-quinolylcarbamoyl)nonane 以 乙醇 为溶剂， 以77%的产率得到
  参考文献：
  名称：

  Synthesis and properties of transition-metal complexes of 5,5-bis(N-8-quinolylcarbamoyl)nonane

  摘要：

  Several metal complexes of 5,5-bis(N-8-quinolylcarbamoyl)nonane (H2L1) and the copper(II) complex of 5,5-bis(N-2-methyl-8-quinolylcarbamoyl)nonane (H2L2) have been synthesised and their spectroscopic properties studied. Whereas complexes of Cu, Ni, Pd, Zn and Cd with H2L1 were obtained, no complex with Co and Pt could be isolated. On the other hand, the copper complex of H2L2 was readily obtained, but the nickel complex could not be isolated. These compounds can be formulated as [ML] in which the amide groups of H2L1 and H2L2 are fully deprotonated. They were characterized by mass, IR and H-1 NMR spectroscopy. Their ultraviolet-visible, luminescence and redox properties were also investigated.

  DOI：

  10.1039/dt9910001483
• 作为产物：
  描述：

  二丁基丙二酸 在 氯化亚砜 作用下， 以 苯 为溶剂， 反应 4.0h， 生成 5,5-bis-(N-2-methyl-8-quinolylcarbamoyl)nonane
  参考文献：
  名称：

  Synthesis and properties of transition-metal complexes of 5,5-bis(N-8-quinolylcarbamoyl)nonane

  摘要：

  Several metal complexes of 5,5-bis(N-8-quinolylcarbamoyl)nonane (H2L1) and the copper(II) complex of 5,5-bis(N-2-methyl-8-quinolylcarbamoyl)nonane (H2L2) have been synthesised and their spectroscopic properties studied. Whereas complexes of Cu, Ni, Pd, Zn and Cd with H2L1 were obtained, no complex with Co and Pt could be isolated. On the other hand, the copper complex of H2L2 was readily obtained, but the nickel complex could not be isolated. These compounds can be formulated as [ML] in which the amide groups of H2L1 and H2L2 are fully deprotonated. They were characterized by mass, IR and H-1 NMR spectroscopy. Their ultraviolet-visible, luminescence and redox properties were also investigated.

  DOI：

  10.1039/dt9910001483

文献信息

• Hiratani, Kazuhisa; Taguchi, Kazuhiro; Ohhashi, Kozaburo, Chemistry Letters, 1989, p. 2073 - 2076
  作者：Hiratani, Kazuhisa、Taguchi, Kazuhiro、Ohhashi, Kozaburo、Nakayama, Hiroshi

  DOI：——

  日期：——