7-Isopropoxy-2,2,4-trimethyl-1-(3-methyl-but-2-enyl)-1,2,3,4-tetrahydro-quinoline | 917096-14-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 7-Isopropoxy-2,2,4-trimethyl-1-(3-methyl-but-2-enyl)-1,2,3,4-tetrahydro-quinoline
• CAS: 917096-14-1
• 化学式: C₂₀H₃₁NO
• 分子量: 301.472
• InChiKey: NUMMUGQPQFQXCJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.53
• 重原子数：
  22.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  12.47
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  7-Isopropoxy-2,2,4-trimethyl-1-(3-methyl-but-2-enyl)-1,2,3,4-tetrahydro-quinoline 在 acid 作用下， 生成 8-hydroxy-1,3,3,7,7-penta-methyl-julolidine
  参考文献：
  名称：

  Efficient Green Coumarin Dopants for Organic Light-Emitting Devices

  摘要：

  [GRAPHICS]We have synthesized a new green fluorescent dopant C-545P having incorporated five strategically placed "methyl" steric spacers on the julolidyl ring system. C-545P has good thermal properties and photostability, and when fabricated as a dopant in an Alq(3)-hosted OLED device, it shows notable improvement in luminance efficiency and is more resistant to concentration quenching than C-545T, particularly in the doping concentration range between 1 and 2% v/v, while achieving comparable device stability.

  DOI：

  10.1021/ol049903d
• 作为产物：
  描述：

  3-氨基苯酚 在 氢氧化钾 、 氢气 、 碘 作用下， 以 二甲基亚砜 为溶剂， 生成 7-Isopropoxy-2,2,4-trimethyl-1-(3-methyl-but-2-enyl)-1,2,3,4-tetrahydro-quinoline
  参考文献：
  名称：

  Efficient Green Coumarin Dopants for Organic Light-Emitting Devices

  摘要：

  [GRAPHICS]We have synthesized a new green fluorescent dopant C-545P having incorporated five strategically placed "methyl" steric spacers on the julolidyl ring system. C-545P has good thermal properties and photostability, and when fabricated as a dopant in an Alq(3)-hosted OLED device, it shows notable improvement in luminance efficiency and is more resistant to concentration quenching than C-545T, particularly in the doping concentration range between 1 and 2% v/v, while achieving comparable device stability.

  DOI：

  10.1021/ol049903d