Zn(1,10-phenanthroline)(H3adip)2 | 905723-16-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: Zn(1,10-phenanthroline)(H3adip)2
• 英文别名: Zn(phen)(H3adip)2
• CAS: 905723-16-2
• 化学式: C₃₆H₂₈N₄O₁₆Zn
• 分子量: 838.026
• InChiKey: LTACJINYMLIUEZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  5-aminodiacetic isophthalic acid 、 1,10-菲罗啉 、 zinc(II) acetate dihydrate 以 水 为溶剂， 以36.2%的产率得到Zn(1,10-phenanthroline)(H3adip)2
  参考文献：
  名称：

  Blue luminescent complexes based on 5-aminodiacetic isophthalic ligand

  摘要：

  The reactions of Cd(CH3COO)(2)center dot 2H(2)O or Zn(CH3COO)(2)center dot 2H(2)O and 5-aminodiacetic isophthalic acid (H(4)adip) with 1,10'-phenanthroline (phen) ligand gave rise to two blue luminescent coordination mononuclear complexes: [Cd(phen)(H(3)adip)(2)(H2O)(2)]center dot-0.5H(2)O (1) and Zn(phen)(H(3)adip)(2) (2), respectively. 1 crystallizes in the triclinic space group P-1, with a=6.2889(2), b=16.1556(5), c=18.4277(7) angstrom, alpha=97.722(12), beta=94.338(9), gamma=95.039(7)degrees, V=1840.86(11) angstrom(3), Z=2. Complex 2 crystallizes in monoclinic, space group C2/c with a=22.639(8),b=9.813(3),c=15.708(6)angstrom,beta=110.928(4)degrees,V=3259(2) angstrom(3), Z=4. Carboxylic groups in both structures are involved in strong hydrogen bonding interactions. At room temperature, complex I exhibits an intense emission at 474 nm upon 380 nm excitation, while complex 2 exhibits an intense emission at 485 nm upon 365 nm excitation, which are contributed from ligand-to-metal charge-transfer (LMCT). (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2005.12.023