α,α-diallyl-o-hydroxyacetophenone | 93912-00-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: α,α-diallyl-o-hydroxyacetophenone
• 英文别名: 1-(2-Hydroxyphenyl)-2-prop-2-enylpent-4-en-1-one
• CAS: 93912-00-6
• 化学式: C₁₄H₁₆O₂
• 分子量: 216.28
• InChiKey: SPVYMWIJYZXAHU-UHFFFAOYSA-N

物化性质

• 沸点：
  337.8±37.0 °C(Predicted)
• 密度：
  1.034±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2'-羟基苯乙酮 、 烯丙醇 在 palladium diacetate 三乙基硼 、 三苯基膦 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以82%的产率得到α,α-diallyl-o-hydroxyacetophenone
  参考文献：
  名称：

  Et3B-promoted, Pd-catalyzed C-allylation of o-hydroxyacetophenone and its derivatives with allyl alcohols

  摘要：

  Triethylborane promotes the Pd-catalyzed selective C-diallylation of o-hydroxyacetophenone and C-monoallylation of o-hydroxypropiophenone with a variety of ally alcohols. The reaction proceeds smoothly at 25-50 degreesC and provides the allylation products in excellent yields, (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)00381-1

文献信息

• Majumdar; Khan; Chattopadhyay, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1990, vol. 29, # 5, p. 483 - 485
  作者：Majumdar、Khan、Chattopadhyay

  DOI：——

  日期：——
• MAJUMDAR, K. C.;KHAN, A. T.;CHATTOPADHYAY, S. K., INDIAN J. CHEM. B, 29,(1990) N, C. 483-485
  作者：MAJUMDAR, K. C.、KHAN, A. T.、CHATTOPADHYAY, S. K.

  DOI：——

  日期：——
• INK JET INK COMPOSITION AND METHOD FOR SECURITY MAKING
  申请人：Videojet Technologies Inc.

  公开号：EP1601729A1

  公开（公告）日：2005-12-07
• [EN] PHOTOCURABLE COMPOSITION FOR PREPARING LENSES<br/>[FR] COMPOSITION PHOTODURCISSABLE POUR LA PREPARATION DE LENTILLES
  申请人：SOLA INT HOLDINGS

  公开号：WO2000064956A1

  公开（公告）日：2000-11-02

  A photocurable composition for preparation of a lens including: a polythiol compound; an aromatic monomer containing at least two vinyl groups; an acrylate monomer containing at least two unsaturated groups and selected from the group consisting of acrylates, methacrylates, acrylic acid anhydrides and methacylic anhydrides; and a photoinitiator.
• [EN] INK JET INK COMPOSITION AND METHOD FOR SECURITY MAKING<br/>[FR] COMPOSITION D'ENCRAGE POUR IMPRIMANTE A JET D'ENCRE ET PROCEDE DE FABRICATION SECURITAIRE
  申请人：VIDEOJET TECHNOLOGIES LTD

  公开号：WO2004081125A1

  公开（公告）日：2004-09-23

  Disclosed is an ink composition suitable for ink jet printing comprising a luminescent compound, a solvent, and an energy active compound, and optionally a non-luminescent colorant. The energy active compound, when exposed to energy, generates one or more active species that can react with the luminescent compound to alter one or more of the characteristics of the luminescent compound. The luminescent compound can be colored or colorless. Also disclosed is a method for marking substrates comprising providing a mark comprising a luminescent compound and an energy active compound. Further disclosed is a jet ink composition suitable for printing on substrates authentication or security marks which can be rendered unreadable. The luminescence of the mark is quenched and the visible color is changed when irradiated with a light.