| 170947-54-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• CAS: 170947-54-3
• 化学式: C₂₈H₃₂O₈
• 分子量: 496.557
• InChiKey: BUUWVNOBNBGGSM-TVNUFPKPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.32
• 重原子数：
  36.0
• 可旋转键数：
  4.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  105.2
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  环戊二烯 、 以72%的产率得到
  参考文献：
  名称：

  Cavity-shaped molracs with inward-facing, direct line-of-sight functionality

  摘要：

  New rigid cavity molecules are described in which bromides, epoxides, olefins, alcohols and acetates are positioned such that there is direct line of sight between them. Examples are provided of systems where the separation distances are in the range from 4-7 Angstrom, although the principles espoused allow production of molecules with significantly larger separation.

  DOI：

  10.1016/0040-4039(95)01164-d
• 作为产物：
  描述：

  丁炔二酸二甲酯 、 (1α,4α,4aα,10aα,5α,8α,8aα,9aα)-1,4,4a,5,8,8a,9,9a,10,10a-decahydro-1,4:5,8-dimethanoanthracene 在 钌 作用下， 以51%的产率得到
  参考文献：
  名称：

  Cavity-shaped molracs with inward-facing, direct line-of-sight functionality

  摘要：

  New rigid cavity molecules are described in which bromides, epoxides, olefins, alcohols and acetates are positioned such that there is direct line of sight between them. Examples are provided of systems where the separation distances are in the range from 4-7 Angstrom, although the principles espoused allow production of molecules with significantly larger separation.

  DOI：

  10.1016/0040-4039(95)01164-d

文献信息

• Rigid molecular racks featuring the 1,10-phenanthroline ligand especially those co-functionalised with redox-active groups or other bidentate ligands
  作者：Ronald N. Warrener、Austin C. Schultz、Mark A. Houghton、Douglas N. Butler

  DOI：10.1016/s0040-4020(97)00014-8

  日期：1997.3

  stereospecificity. Bridged 1,10-phenanthrolines with different separation distances and ligand, ligand orientations have been prepared and mixed ligand systems are described with diazafluorene and 3,6-di(2-pyridyl)pyridazine ligand components. New diad and triad systems are reported which contain redox-active components linked to ligand centres. The rigid nature of the polyalicyclic molrac framework and the fusion

  首次制备的6,7-二氮杂苯环酮（DAPC）以二聚体形式存在，但与单体11处于热平衡状态在解决方案中。DAPC是一种反应性二烯，可与具有高立体特异性的环应变和缺电子的二烯亲核体发生反应。制备了具有不同分离距离和配体的桥连的1,10-菲咯啉，配体的取向和混合的配体体系与二氮杂芴和3,6-二（2-吡啶基）哒嗪配体组成一起描述。据报道，新的二元组和三元组系统包含与配体中心相连的氧化还原活性成分。聚脂环莫拉克骨架的刚性性质和用于连接官能团的融合方法为分子提供了精确的生色团几何定位和取向。这使得这些系统成为研究电子转移和能量转移过程的关键分子。