3,8-bis(1-naphthyl)-1,10-phenanthroline | 709022-71-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 3,8-bis(1-naphthyl)-1,10-phenanthroline
• 英文别名: 3,8-di-(1-naphthyl)-1,10-phenanthroline；3,8-Dinaphthalen-1-yl-1,10-phenanthroline；3,8-dinaphthalen-1-yl-1,10-phenanthroline
• CAS: 709022-71-9
• 化学式: C₃₂H₂₀N₂
• 分子量: 432.524
• InChiKey: MSTUPORHCFOHOX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  34
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3,8-bis(1-naphthyl)-1,10-phenanthroline 、 zinc(II) chloride 以 甲醇 、 乙酸乙酯 、 甲苯 为溶剂， 以89%的产率得到[Zn(II)(3,8-bis(1-naphthyl)-1,10-phenanthroline)2]Cl2
  参考文献：
  名称：

  Synthesis and photophysical processes of a novel 1,10-phenanthroline-containing p-conjugated chromophores and Zn(II) chelated complex

  摘要：

  A novel 1,10-phenanthroline-containing p-conjugated chromophore, 3,8-di-(1-naphthyl)-1,10-phenanthroline, was synthesized by Suzuki reaction and its chelated complex was prepared. The UV-visible spectroscopy and photoluminescent (PL) properties were investigated. The results show that when the solution of the complex in THF located in low concentration range (< 10(-6) mol/L), the fluorescence emission exhibit only one emission band and the excimer is formed with gradual increase in concentration of the complex. The emission spectra of the complex show obvious solvent effect. In addition, the intermolecular action between the complex and fullerene (C-60) were investigated. The fluorescence intensity of the complex is decreased and the maximal emission obvious red-shifted with the increasing of the concentration of C-60, which suggests that the strong interactions between the complex and C-60 happen in the excited state. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2006.06.009
• 作为产物：
  描述：

  3,8-二溴菲罗啉 、 1-萘硼酸 在 palladium diacetate 、 sodium carbonate 、 三苯基膦 作用下， 以 水 、 甲苯 为溶剂， 生成 3,8-bis(1-naphthyl)-1,10-phenanthroline
  参考文献：
  名称：

  Synthesis and photophysical processes of a novel 1,10-phenanthroline-containing p-conjugated chromophores and Zn(II) chelated complex

  摘要：

  A novel 1,10-phenanthroline-containing p-conjugated chromophore, 3,8-di-(1-naphthyl)-1,10-phenanthroline, was synthesized by Suzuki reaction and its chelated complex was prepared. The UV-visible spectroscopy and photoluminescent (PL) properties were investigated. The results show that when the solution of the complex in THF located in low concentration range (< 10(-6) mol/L), the fluorescence emission exhibit only one emission band and the excimer is formed with gradual increase in concentration of the complex. The emission spectra of the complex show obvious solvent effect. In addition, the intermolecular action between the complex and fullerene (C-60) were investigated. The fluorescence intensity of the complex is decreased and the maximal emission obvious red-shifted with the increasing of the concentration of C-60, which suggests that the strong interactions between the complex and C-60 happen in the excited state. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2006.06.009

文献信息

• ORGANIC ELECTROLUMINESCENT ELEMENT AND ELECTRONIC DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20160197289A1

  公开（公告）日：2016-07-07

  An organic electroluminescence device includes: an anode; a cathode opposite the anode; and an organic layer interposed between the anode and the cathode, in which the organic layer includes: an emitting layer; and a first electron transporting layer and a second electron transporting layer which are provided on a side of the emitting layer near the cathode. The first electron transporting layer includes a compound represented by a formula (1) below, and the second electron transporting layer includes a compound represented by a formula (2) below.