2,2-dimethyl-1-phenyl-hexan-1-one | 17234-63-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,2-dimethyl-1-phenyl-hexan-1-one
• 英文别名: 2,2-Dimethyl-1-phenyl-hexan-1-on；ω.ω-Dimethyl-ω-butyl-acetophenon；α.α-Dimethyl-caprophenon；1-Oxo-2.2-dimethyl-1-phenyl-hexan；1-Phenyl-2,2-dimethyl-1-hexanon；2,2-Dimethyl-1-phenyl-1-hexanone；2,2-dimethyl-1-phenylhexan-1-one
• CAS: 17234-63-8
• 化学式: C₁₄H₂₀O
• 分子量: 204.312
• InChiKey: JUZFGMACIAYZCN-UHFFFAOYSA-N

物化性质

• 沸点：
  110-111 °C(Press: 0.5 Torr)
• 密度：
  0.928±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2,2-dimethyl-1-phenyl-hexan-1-one 在 sodium amide 、 甲苯 作用下， 生成 2,2-二甲基己酰胺
  参考文献：
  名称：

  Blondeau, Bulletin de la Societe Chimique de France, 1928, vol. <4>43, p. 345

  摘要：

  DOI：
• 作为产物：
  描述：

  2-甲基-2,4-戊二醇 在 硫酸 作用下， 生成 2,2-dimethyl-1-phenyl-hexan-1-one
  参考文献：
  名称：

  Chemistry of dihydro-1,3-oxazines. XX. Synthesis of .alpha.-branched ketones from dihydro-1,3-oxazines via the ketenimine intermediate. .alpha.-Substituted ketones from a stable ketenimine

  摘要：

  DOI：

  10.1021/jo00952a004

文献信息

• Bruzau, Annales de Chimie (Cachan, France), 1934, vol. <11> 1, p. 257,276
  作者：Bruzau

  DOI：——

  日期：——
• Photochemical synthesis. 65. Thione photochemistry. 22. Intramolecular cyclization of aralkyl thiones from S2
  作者：A. Couture、K. Ho、M. Hoshino、P. De Mayo、R. Suau、W. R. Ware

  DOI：10.1021/ja00436a025

  日期：1976.9
• Grammaticakis, Bulletin de la Societe Chimique de France, 1950, p. 504,506
  作者：Grammaticakis

  DOI：——

  日期：——
• Ramart-Lucas; Hoch, Bulletin de la Societe Chimique de France, 1938, vol. <5> 5, p. 987,1007
  作者：Ramart-Lucas、Hoch

  DOI：——

  日期：——
• (RE)PLACING THE NEW URBANISM DEBATES: TOWARD AN INTERDISCIPLINARY RESEARCH AGENDA
  作者：Karen Falconer Al-Hindi、Karen E. Till

  DOI：10.2747/0272-3638.22.3.189

  日期：2001.4

  New Urbanism (NU) is a complex planning paradigm and social movement that has recently become influential in planning, residential development, and government housing circles. To introduce this special issue on NU, we describe the history and important figures of the movement and provide a brief literature review of popular, academic, and professional presses. Because NU is a multifaceted phenomenon, we advocate an interdisciplinary approach to understanding it, one that would promote constructive dialogue and a range of perspectives (and choices) within and between disciplines, professions, and communities. From the vantage point of the academic community (in particular, geography), we argue that various theoretical and methodological perspectives can contribute to a more progressive understanding and implementation of NU practices at various scales. We conclude by outlining three areas for future research documenting how NU is understood and implemented by urban professionals, analyzing urban infill projects, and conducting ethnographies of neotraditional towns.