(2R,6R,10R)-6,10,14-trimethylpentadecane-2-ol hemisuccinate | 1290041-52-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (2R,6R,10R)-6,10,14-trimethylpentadecane-2-ol hemisuccinate
• 英文别名: 4-oxo-4-[(2R,6R,10R)-6,10,14-trimethylpentadecan-2-yl]oxybutanoic acid
• CAS: 1290041-52-9
• 化学式: C₂₂H₄₂O₄
• 分子量: 370.573
• InChiKey: PXUVKAWFDHVUBI-VAMGGRTRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  26
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (2R,6R,10R)-6,10,14-trimethylpentadecane-2-ol hemisuccinate 在 甲醇 、 sodium 作用下， 反应 0.5h， 以93%的产率得到(2R,6R,10R)-6,10,14-trimethylpentadecane-2-ol
  参考文献：
  名称：

  Chemoenzymatic synthesis of (2R,6R,10R)-6,10,14-trimethylpentadecan-2-ol, sex pheromone of rice moth (Corcyra cephalonica), and of its (2S,6R,10R)-diastereomer

  摘要：

  Based on the catalyzed by lipase Amano PS kinetic separation of the two-component mixture of diastereomers of (2RS,6R,10R)-6,10,14-trimethylpentadecan-2-ol in the acylation with the succinic anhydride we obtained the (2R,6R,10R)-6,10,14-trimethylpentadecan-2-ol, the sex pheromone of rice moth (Corcyra cephalonica) and its (2S,6R,10R)-diastereomer.

  DOI：

  10.1134/s1070428011020217
• 作为产物：
  描述：

  (6R,10R)-6,10,14-trimethylpentadecan-2-one 在 sodium tetrahydroborate 作用下， 以 甲醇 、 异丙醚 为溶剂， 反应 4.0h， 生成 (2R,6R,10R)-6,10,14-trimethylpentadecane-2-ol hemisuccinate 、 (2S,6R,10R)-6,10,14-trimethylpentadecane-2-ol
  参考文献：
  名称：

  Chemoenzymatic synthesis of (2R,6R,10R)-6,10,14-trimethylpentadecan-2-ol, sex pheromone of rice moth (Corcyra cephalonica), and of its (2S,6R,10R)-diastereomer

  摘要：

  Based on the catalyzed by lipase Amano PS kinetic separation of the two-component mixture of diastereomers of (2RS,6R,10R)-6,10,14-trimethylpentadecan-2-ol in the acylation with the succinic anhydride we obtained the (2R,6R,10R)-6,10,14-trimethylpentadecan-2-ol, the sex pheromone of rice moth (Corcyra cephalonica) and its (2S,6R,10R)-diastereomer.

  DOI：

  10.1134/s1070428011020217

文献信息

• Chemoenzymatic synthesis of (2R,6R,10R)-6,10,14-trimethylpentadecan-2-ol, sex pheromone of rice moth (Corcyra cephalonica), and of its (2S,6R,10R)-diastereomer
  作者：R. V. Shafikov、A. Yu. Spivak、V. N. Odinokov

  DOI：10.1134/s1070428011020217

  日期：2011.2

  Based on the catalyzed by lipase Amano PS kinetic separation of the two-component mixture of diastereomers of (2RS,6R,10R)-6,10,14-trimethylpentadecan-2-ol in the acylation with the succinic anhydride we obtained the (2R,6R,10R)-6,10,14-trimethylpentadecan-2-ol, the sex pheromone of rice moth (Corcyra cephalonica) and its (2S,6R,10R)-diastereomer.