1-[4'-(2-methyl-[1,3]dioxolan-2-yl)-biphenyl-4-yl]-ethanone | 1258973-51-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-[4'-(2-methyl-[1,3]dioxolan-2-yl)-biphenyl-4-yl]-ethanone
• CAS: 1258973-51-1
• 化学式: C₁₈H₁₈O₃
• 分子量: 282.339
• InChiKey: URXDPHRGRSLKDN-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  4-碘代苯乙酮 、 在 potassium acetate 、 palladium diacetate 、 二环己胺 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 2.0h， 以60%的产率得到1-[4'-(2-methyl-[1,3]dioxolan-2-yl)-biphenyl-4-yl]-ethanone
  参考文献：
  名称：

  Pd-catalyzed coupling of aryl iodides with triarylbismuths as atom-economic multi-coupling organometallic nucleophiles under mild conditions

  摘要：

  The facile cross-coupling reactivity of triarylbismuth compounds with aryl iodides was achieved under mild heating conditions. The established catalytic protocol using Pd(OAc)(2)(Cy2NH)(2) system exhibited high coupling reactivity with a variety of triarylbismuth and aryl iodide compounds under mild conditions. These coupling reactions were completed in short reaction time affording good to high yields of functionalized biaryl products. The studies of multi-coupling reactions with tris(4-iodophenyl)amine, 8 also furnished moderate to good yields of coupled products, 8a-8f. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.09.053