(η(5)-cyclopentadienyl)-[(4-6-η(3))-2-aza-2-cyclohexyl-4-methyl-1-oxo-4-hexen-1,6-diyl]-cobalt(III) | 247144-55-4

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: (η(5)-cyclopentadienyl)-[(4-6-η(3))-2-aza-2-cyclohexyl-4-methyl-1-oxo-4-hexen-1,6-diyl]-cobalt(III)
• 英文别名: cobalt(3+);[cyclohexyl-[(Z)-2-methylbut-2-enyl]amino]methanone;cyclopenta-1,3-diene
• CAS: 247144-55-4
• 化学式: C₁₇H₂₄CoNO
• 分子量: 317.377
• InChiKey: CCNXWNNGOTXQMU-APRVNQMFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η(5)-cyclopentadienyl)-[(4-6-η(3))-2-aza-2-cyclohexyl-4-methyl-1-oxo-4-hexen-1,6-diyl]-cobalt(III) 、 trimethoxonium tetrafluoroborate 以 二氯甲烷 为溶剂， 以82%的产率得到(η(5)-cyclopentadienyl)-[(4-6-η(3))-2-aza-2-cyclohexyl-1-methoxy-4-methyl-4-hexen-6-yl-1-ylidene]cobalt(III) tetrafluoroborate
  参考文献：
  名称：

  The chemistry of metallacyclic alkenylcarbene complexes

  摘要：

  Cobaltalactams 7 with alkyl substituents at the nitrogen atom are accessible by W-irradiation of CpCo(CO)(2) 6 in the presence of the appropriate vicinal aminoalkenol 8. Thus chelated (eta 3-allyl)cobaltcarbene complexes with either (endo-amino)oxo (3), (exo-amino)oxo (11), or dioxo (2) substitution at the carbene carbon atom are now available. A synthetic route to chelated (eta(2)-alkene)-carbene complexes of chromium with allylically situated hydroxy groups is also presented. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00203-x
• 作为产物：
  描述：

  carbon monoxide,cobalt,cyclopenta-1,3-diene 、 1-cyclohexylamino-2-methyl-3-buten-2-ol 以 四氢呋喃 为溶剂， 以31%的产率得到(η(5)-cyclopentadienyl)-[(4-6-η(3))-2-aza-2-cyclohexyl-4-methyl-1-oxo-4-hexen-1,6-diyl]-cobalt(III)
  参考文献：
  名称：

  The chemistry of metallacyclic alkenylcarbene complexes

  摘要：

  Cobaltalactams 7 with alkyl substituents at the nitrogen atom are accessible by W-irradiation of CpCo(CO)(2) 6 in the presence of the appropriate vicinal aminoalkenol 8. Thus chelated (eta 3-allyl)cobaltcarbene complexes with either (endo-amino)oxo (3), (exo-amino)oxo (11), or dioxo (2) substitution at the carbene carbon atom are now available. A synthetic route to chelated (eta(2)-alkene)-carbene complexes of chromium with allylically situated hydroxy groups is also presented. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00203-x