磷酸一丁基单苯酯 | 46438-39-5

• 物质功能分类: 有机原料 - 无机酸酯
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 磷酸一丁基单苯酯
• 英文名称: Butyl-phenyl-phosphat
• 英文别名: Phosphorsaeure-butylester-phenylester；Butyl phenyl hydrogen phosphate
• CAS: 46438-39-5
• 化学式: C₁₀H₁₅O₄P
• 分子量: 230.2
• InChiKey: GTORMKXYQMWBEP-UHFFFAOYSA-N

物化性质

• 沸点：
  325.1±25.0 °C(Predicted)
• 密度：
  1.205±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

安全信息

• 海关编码：
  2919900090

反应信息

• 作为反应物：
  描述：

  氯磷酸丁基苯基酯 、 磷酸一丁基单苯酯 在 吡啶 作用下， 以 苯 为溶剂， 生成 Bis(phosphoric Acid Butyl Phenyl Ester) Anhydride
  参考文献：
  名称：

  Korth, Hans-Gert; Lommes, Petra, Chemische Berichte, 1992, vol. 125, # 11, p. 2419 - 2438

  摘要：

  DOI：
• 作为产物：
  描述：

  氯磷酸丁基苯基酯 在 水 作用下， 以75.5%的产率得到磷酸一丁基单苯酯
  参考文献：
  名称：

  Korth, Hans-Gert; Lommes, Petra, Chemische Berichte, 1992, vol. 125, # 11, p. 2419 - 2438

  摘要：

  DOI：

文献信息

• METHODS OF SYNTHESIZING A POLYNUCLEOTIDE ARRAY USING PHOTOACTIVATED AGENTS
  申请人：Vibrant Holdings, LLC

  公开号：US20210380629A1

  公开（公告）日：2021-12-09

  Described herein are methods for the synthesis of DNA polynucleotides and polynucleotides, as well as methods for their deprotection and methods for the use of said compounds and compositions comprising said compounds. In particular, such compounds and compositions comprising them are used in methods for light-directed synthesis of DNA microarrays.

  本文描述了合成DNA多核苷酸和多核苷酸的方法，以及它们的去保护方法、使用这些化合物的方法和包含这些化合物的组合物的方法。特别是，这些化合物和包含它们的组合物用于DNA微阵列的光导向合成方法。
• POLYAMIDE RESIN AND USE THEREOF AND POLYAMIDE COMPOSITION CONSISTING OF SAME
  申请人：Kingfa Sci&Tech Co. Ltd.

  公开号：EP2944665A1

  公开（公告）日：2015-11-18

  The present invention discloses a polyamide resin and its application and polyamide composition thereof. The repeating units of the described polyamide resin comprises the following components: dicarboxylic acid units composed 80-100mol% of polyamide resin; aliphatic diamines units having 2-14 carbon atoms composed 80-100mol% of polyamide resin; lactam or amino acid units having 6-14 carbon atoms composed 0-20mol% of polyamide resin; in the described polyamide resin, the bio-based carbon concentration is more than 45%; the described bio-based carbon mole concentration is calculated according to the formula below: bio-based carbon concentration=(bio-based carbon mole content/total organic carbon mole content)*100%. The described polyamide resin in the present invention has low gas volatile, hence the polyamide composition produced thereof has low gas volatile too, and can be applied to food-contact field. In addition, the surface condition after reflow soldering of the polyamide composition produced is good.

  本发明公开了一种聚酰胺树脂及其应用和聚酰胺组合物。所述聚酰胺树脂的重复单元由以下组分组成：二羧酸单元占聚酰胺树脂的 80-100mol%；具有 2-14 个碳原子的脂肪族二胺单元占聚酰胺树脂的 80-100mol%；具有 6-14 个碳原子的内酰胺或氨基酸单元占聚酰胺树脂的 0-20mol%；在所述聚酰胺树脂中，生物基碳浓度大于 45%；所述生物基碳摩尔浓度按下式计算：生物基碳浓度=（生物基碳摩尔含量/总有机碳摩尔含量）*100%。本发明中所述聚酰胺树脂的气体挥发性较低，因此其生产的聚酰胺组合物的气体挥发性也较低，可应用于食品接触领域。此外，生产的聚酰胺组合物在回流焊接后的表面状况良好。
• COMPOSITION FOR HYDROPHILIC CURED PRODUCT
  申请人：Mitsui Chemicals, Inc.

  公开号：EP3081578A1

  公开（公告）日：2016-10-19

  Objects of the present invention are to provide a composition which can easily give cured products enriched with hydrophilic groups at the surface, and a composition which can give cured products while ensuring that the surface is enriched with hydrophilic groups which are hardly concentrated at the surface by conventional methods; to provide cured products obtained from such compositions; to provide a composition which is suited for producing cured products having high and long-lasting hydrophilicity and also having high surface smoothness; and to provide a cured product obtained from the composition. A monolayer film is fabricated which includes a crosslinked resin obtained by polymerizing a composition including a compound (I) having at least one hydrophilic group selected from anionic hydrophilic groups, cationic hydrophilic groups and hydroxyl groups, and at least one functional group with a polymerizable carbon-carbon double bond (wherein the number of the functional groups with a polymerizable carbon-carbon double bond is one when the hydrophilic group is a hydroxyl-containing group); a compound (II) having two or more functional groups with a polymerizable carbon-carbon double bond (wherein the compound may have a hydroxyl group but is free from anionic hydrophilic groups and cationic hydrophilic groups); and at least one compound selected from a surfactant (III) having a hydrophilic moiety including an anionic hydrophilic group, a cationic hydrophilic group or two or more hydroxyl groups, and a hydrophobic moiety including an organic residue, and a compound (IV) having a siloxane bond and a molecular weight of 200 to 1,000,000 (wherein the surfactant (III) and the compound (IV) have no polymerizable carbon-carbon double bonds). The monolayer film has a gradient of hydrophilic group concentration (Sa/Da) of not less than 1.1 wherein Sa is the surface concentration of at least one type of hydrophilic groups selected from anionic hydrophilic groups, cationic hydrophilic groups and hydroxyl groups, and Da is the deep concentration of the hydrophilic groups at 1/2 of the thickness of the monolayer film.

  本发明的目的是提供一种组合物，该组合物可以很容易地得到表面富含亲水基团的固化产品，以及一种组合物，该组合物可以在得到固化产品的同时确保表面富含亲水基团，而通过传统方法，亲水基团很难集中在表面上；提供由这种组合物得到的固化产品；提供一种组合物，该组合物适合生产具有高且持久亲水性的固化产品，同时还具有高表面光滑度；以及提供由该组合物得到的固化产品。本发明制备了一种单层膜，该单层膜包括通过聚合一种组合物而获得的交联树脂，该组合物包括一种化合物 (I)，该化合物具有至少一个亲水基团，该亲水基团选自阴离子亲水基团、阳离子亲水基团和羟基，以及至少一个具有可聚合碳碳双键的官能团（其中当亲水基团为含羟基基团时，具有可聚合碳碳双键的官能团的数目为一个）；具有两个或两个以上具有可聚合碳碳双键的官能团的化合物 (II)（其中该化合物可具有羟基，但不含阴离子亲水基团和阳离子亲水基团）；以及至少一种选自表面活性剂（III）的化合物，该表面活性剂具有包括阴离子亲水基团、阳离子亲水基团或两个或多个羟基在内的亲水分子，以及包括有机残留物在内的疏水分子，以及具有硅氧烷键且分子量在 200-1,000,000 之间的化合物（IV）（其中表面活性剂（III）和化合物（IV）不具有可聚合的碳碳双键）。单层膜的亲水基团浓度梯度（Sa/Da）不小于 1.1，其中 Sa 是选自阴离子亲水基团、阳离子亲水基团和羟基的至少一种亲水基团的表面浓度，Da 是亲水基团在单层膜厚度的 1/2 处的深度浓度。
• MODIFIED ACRYLIC RESIN CURED PRODUCT, AND LAMINATE THEREOF, AND PRODUCTION METHODS THEREFOR
  申请人：Mitsui Chemicals, Inc.

  公开号：EP3263635A1

  公开（公告）日：2018-01-03

  The purpose of the present invention is to provide a modified acrylic resin cured product, particularly, a modified acrylic resin film, having excellent lubricity and excellent transparency, and a laminate including the modified acrylic resin film. The modified acrylic resin cured product (C) according to the present invention is obtained by treating the surface of a cured product (X) including an acrylic resin by using a compound (A) containing, in each molecule, one or more anionic hydrophilic groups forming an ion pair with an onium ion of an amino silicone, and one or more groups selected from the group consisting of a group containing a polymerizable carbon-carbon double bond, an amino group, a mercapto group and a hydroxy group.

  本发明的目的是提供一种改性丙烯酸树脂固化物，特别是改性丙烯酸树脂薄膜，它具有极佳的润滑性和极佳的透明度，以及一种包括改性丙烯酸树脂薄膜的层压板。根据本发明的改性丙烯酸树脂固化物（C）是通过使用化合物（A）处理包括丙烯酸树脂的固化物（X）的表面而获得的，化合物（A）在每个分子中含有一个或多个阴离子亲水基团，这些基团与氨基硅的鎓离子形成离子对，还含有一个或多个基团，这些基团选自由含有可聚合碳碳双键的基团、氨基、巯基和羟基组成的组。
• FRICTION-CONTROLLING COMPOUND, AND FRICTION-CONTROLLING COMPOSITION CONTAINING SAID FRICTION-CONTROLLING COMPOUND
  申请人：Adeka Corporation

  公开号：EP3722395A1

  公开（公告）日：2020-10-14

  A friction inhibiting compound of the present invention is a friction inhibiting compound including a copolymer (A) that includes a polymerizable monomer (a) and a polymerizable monomer (b) as constituent monomers, wherein the polymerizable monomer (a) includes a specific alkyl acrylate or alkyl methacrylate, the polymerizable monomer(b) is at least one selected from the group consisting of specific hydroxyalkyl acrylates and hydroxyalkyl methacrylates; specific alkyl acrylates and alkyl methacrylates; and aromatic vinyl monomers having 8 to 14 carbon atoms, and a composition ratio of the polymerizable monomer (a) and polymerizable monomer(b) in the copolymer (A), represented by (a):(b), is (10 to 45):(55 to 90) in a molar ratio (provided that a total molar ratio of (a) and (b) is 100), and the weight average molecular weight of the copolymer (A) is 1,000 to 500,000.

  本发明的一种摩擦抑制化合物是包括共聚物（A）的摩擦抑制化合物，共聚物（A）包括作为组成单体的可聚合单体（a）和可聚合单体（b），其中可聚合单体（a）包括特定的丙烯酸烷基酯或甲基丙烯酸烷基酯，可聚合单体（b）是至少选自特定的丙烯酸羟烷基酯和甲基丙烯酸羟烷基酯组成的组中的一种；可聚合单体(a)和可聚合单体(b)在共聚物(A)中的组成比例为(a)：(b) 的摩尔比为 (10 至 45)：(55 至 90)（前提是 (a) 和 (b) 的总摩尔比为 100），共聚物 (A) 的重量平均分子量为 1,000 至 500,000。