[Fe2(Ox)4(glydtc)] | 556794-81-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [Fe2(Ox)4(glydtc)]
• CAS: 556794-81-1
• 化学式: C₃₉H₂₇Fe₂N₅O₆S₂
• 分子量: 837.499
• InChiKey: SXACYIQMKSBXEB-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  barium glycinyldithiocarbamate 、 8-羟基喹啉 、 三氯化铁 以 乙醇 、 水 为溶剂， 生成 [Fe2(Ox)4(glydtc)]
  参考文献：
  名称：

  摘要：

  This paper reports the isolation and characterisation of mixed ligand complexes of the types Ba[M(Ox)(2)glydtc], [M'(2)(Ox)(4)glydtc], [M-2(QA)(2)glydtc] and [M'(2)(QA)(4)glydtc] (where glydtc=glycinyldithiocarbamate; HOx=8-hydroxyqinoline; HQA=p-methyl-5-phenylazo-8-hydroxyquinoline and M=Co(II), Ni(II) or Cu(II); M'=Fe(III) or Cr(III). The structures for the complexes have been elucidated on the basis of elemental analysis, electronic, IR and mass spectroscopy. Electronic spectral data for the complexes were in accordance with an octahedral environment around the central metal ions in all metal chelates except for [Co-2(QA)(2)glydtc] and [Ni-2(QA)(2)glydtc] where the structure around Co(II) and Ni(II) may be tetrahedral. The complexes were proposed to be dimeric except those of Ba[M(Ox)(2)glydtc]. A study of the thermal decomposition of the complexes has also been carried out. For Ba [M(Ox)(2)glydtc], elimination of carbon dioxide was observed. However, evolution of nitrogen and formation of tolyl radicals occur for [M-2(QA)(2)glydtc] and [M-2(QA)(4)glydtc]. Kinetic parameters for the various decomposition stages were calculated using the Coats-Redfern and Horowitz-Metzger equations.

  DOI：

  10.1023/a:1016167311977