barium glycinyldithiocarbamate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: barium glycinyldithiocarbamate
• 英文别名: Ba(glydyc)；Barium(2+);2-(sulfidocarbothioylamino)acetate；barium(2+);2-(sulfidocarbothioylamino)acetate
• 化学式: Ba*C₃H₃NO₂S₂
• 分子量: 286.524
• InChiKey: ULABYVQRLBELMK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -2.22
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  85.2
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  barium glycinyldithiocarbamate 、 bis(acetylacetonate)oxovanadium 以 乙醇 、 水 为溶剂， 以80%的产率得到μ-(glycinyldithiocarbamato)bis{(acetylacetonato)oxovanadium(IV)}
  参考文献：
  名称：

  Zidan, Amna S. A.; El-Said, Asma I.; Aly, Aref A. M., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1992, vol. 22, p. 1355 - 1362

  摘要：

  DOI：

文献信息

• Lanthanum(III) and praseodymium(III) derivatives with dithiocarbamates derived from α-amino acids
  作者：Anita Rai、Soumitra K. Sengupta、Om P. Pandey

  DOI：10.1016/j.saa.2005.06.051

  日期：2006.6

  Lanthanum(III) and praseodymium(III) complexes with dithiocarbamates have been synthesized by the reactions of lanthanum(III) and praseodymium(III) chloride with barium dithiocarbamate and complexes of type [LnCl(L)H2O]n have been obtained (where Ln=La(III) or Pr(III); L=barium salt of dithiocarbamate derived from glycine, L-leucine, L-valine, DL-alanine). The complexes have been characterized by elemental

  通过镧（III）和氯化ase（III）与二硫代氨基甲酸钡的反应合成了镧（III）和ase（III）配合物，得到了[LnCl（L）H2O] n类型的配合物（其中Ln ＝ La（III）或Pr（III）； L ＝衍生自甘氨酸，L-亮氨酸，L-缬氨酸，DL-丙氨酸的二硫代氨基甲酸酯的钡盐）。通过元素分析，摩尔电导，电子吸收和荧光，红外，远红外，1H NMR光谱研究对复合物进行了表征。从热重分析可以推断出配位水分子的存在，这表明一个水分子在150-170摄氏度时会损失。对于不同的跃迁，已经获得了振荡器强度，Judd-Ofelt强度参数，受激发射截面等。 Pr3 +。
• Sulphidomolybdenum(V) complexes with amino acid dithiocarbamates
  作者：Vasanthi Lakshmanan、M.R. Udupa、K.S. Nagaraja

  DOI：10.1016/s0277-5387(00)83370-7

  日期：1992.1

  The interaction of ammonium tetrathiomolybdate with the barium salts of the dithiocarbamates (dtc) of glycine, DL-alanine and DL-2-aminobutyric acid yielded Ba[Mo2S4(dtc)2]. The molar conductivities (approximately 50 OMEGA(-1) cm-1) in DMSO indicated the ionic nature of the complexes. The subnormal magnetic moment (0.4 B.M.), electronic and IR spectral data and CVM peak potentials (-0.95 and -1.25 V vs SCE) suggested a dimeric species with a [Mo2S4]2+ core. The IR spectral data suggested the bidentate coordination of the dithiocarbamate groups and the absence of coordination by the carboxylate group. Thermal properties of the complexes are discussed.
• ——
  作者：A. S. A. [e-mail]

  DOI：10.1023/a:1016167311977

  日期：——

  This paper reports the isolation and characterisation of mixed ligand complexes of the types Ba[M(Ox)(2)glydtc], [M'(2)(Ox)(4)glydtc], [M-2(QA)(2)glydtc] and [M'(2)(QA)(4)glydtc] (where glydtc=glycinyldithiocarbamate; HOx=8-hydroxyqinoline; HQA=p-methyl-5-phenylazo-8-hydroxyquinoline and M=Co(II), Ni(II) or Cu(II); M'=Fe(III) or Cr(III). The structures for the complexes have been elucidated on the basis of elemental analysis, electronic, IR and mass spectroscopy. Electronic spectral data for the complexes were in accordance with an octahedral environment around the central metal ions in all metal chelates except for [Co-2(QA)(2)glydtc] and [Ni-2(QA)(2)glydtc] where the structure around Co(II) and Ni(II) may be tetrahedral. The complexes were proposed to be dimeric except those of Ba[M(Ox)(2)glydtc]. A study of the thermal decomposition of the complexes has also been carried out. For Ba [M(Ox)(2)glydtc], elimination of carbon dioxide was observed. However, evolution of nitrogen and formation of tolyl radicals occur for [M-2(QA)(2)glydtc] and [M-2(QA)(4)glydtc]. Kinetic parameters for the various decomposition stages were calculated using the Coats-Redfern and Horowitz-Metzger equations.
• Microwave Assisted Green Synthesis and Entomological Characteristic Studies of Novel Chromium(III) complexes of dithiocarbamates derived from glycine, alanine, proline, Valine and Norvaline α-amino acids
  作者：Surya Mani Pandey、Keerti Saraswat、Ravi Kant、Mohit S. Mishra、Jaya Pandey

  DOI：10.1016/j.jics.2022.100711

  日期：2022.10