| 1415906-81-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1415906-81-8
• 化学式: C₃₄H₅₂O₆
• 分子量: 556.783
• InChiKey: RPXGBWRBVRBDLT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.14
• 重原子数：
  40.0
• 可旋转键数：
  2.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  77.38
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  在 pyridinium chlorochromate 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以35%的产率得到
  参考文献：
  名称：

  Hemicarceplex Formation With a Cyclotriveratrylene-Based Molecular Cage Allows Isolation of High-Purity (≥99.0%) C₇₀ Directly from Fullerene Extracts

  摘要：

  A cyclotriveratrylene-based molecular cage that favors the formation of a room temperature isolable hemicarceplex with C-70, in the presence of C-60, has been developed. Significant differences in the association and dissociation kinetics of the molecular cage and buckyballs allowed the isolation of C-70 in high purity (>= 99.0%) from a commercial fullerene extract without the need for recrystallization or HPLC.

  DOI：

  10.1021/ol3027957
• 作为产物：
  描述：

  1,10-二溴癸烷 在 sodium tetrahydroborate 、 potassium carbonate 、 potassium hydrogencarbonate 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 、 异丙醇 为溶剂， 反应 208.0h， 生成
  参考文献：
  名称：

  Hemicarceplex Formation With a Cyclotriveratrylene-Based Molecular Cage Allows Isolation of High-Purity (≥99.0%) C₇₀ Directly from Fullerene Extracts

  摘要：

  A cyclotriveratrylene-based molecular cage that favors the formation of a room temperature isolable hemicarceplex with C-70, in the presence of C-60, has been developed. Significant differences in the association and dissociation kinetics of the molecular cage and buckyballs allowed the isolation of C-70 in high purity (>= 99.0%) from a commercial fullerene extract without the need for recrystallization or HPLC.

  DOI：

  10.1021/ol3027957

文献信息

• Turn-on Fluorescent Chemosensor Based on an Amino Acid for Pb(II) and Hg(II) Ions in Aqueous Solutions and Role of Tryptophan for Sensing
  作者：Lok Nath Neupane、Joo-Young Park、Ju Hun Park、Keun-Hyeung Lee

  DOI：10.1021/ol3029516

  日期：2013.1.18

  This communication presents a fluorescent chemosensor for detecting Pb(II) and Hg(II) in aqueous solutions. The sensor showed a turn-on response to Pb(II) by an enhancement of emission intensity at 380 nm and to Hg(II) by an enhancement of emission intensities at 380 and 475 nm. We have first characterized a unique function of tryptophan as a ligand as well as a quencher for recognition and fluorescent change by a metal binding event.