5,5'-bis(HCF2(CF2)5CH2OH2)-2,2'-bpy | 1373318-08-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5,5'-bis(HCF2(CF2)5CH2OH2)-2,2'-bpy
• CAS: 1373318-08-1
• 化学式: C₂₆H₁₆F₂₄N₂O₂
• 分子量: 844.387
• InChiKey: XBSWLHCVSSMNKS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.06
• 重原子数：
  54.0
• 可旋转键数：
  19.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  44.24
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  十二氟庚醇 、 5,5'-二溴甲基-2,2'-联吡啶 在 甲醇 、 sodium methylate 作用下， 以 四氢呋喃 为溶剂， 反应 4.0h， 以92%的产率得到5,5'-bis(HCF2(CF2)5CH2OH2)-2,2'-bpy
  参考文献：
  名称：

  Synthesis and characterization of polyfluorinated 2,2′-bipyridines and their palladium and platinum complexes, [MX2(bis(RfCH2OCH2)-2,2′-bpy)] (X=Cl, Br)

  摘要：

  The fluorous-ponytailed bpy ligands at 4,4' and 5,5'-positions, 4,4'-bis(RfCH2OCH2)-2,2'-bpy and 5,5'-bis(RfCH2OCH2)-2,2'bpy, were prepared. Then these two differently positioned bpy ligands with varying fluorous lengths were treated with [PdCl2(CH3CN)(2)], [PtCl2(CH3CN)(2)], or the simple PtBr2 salt to result in the corresponding 4,4'- or 5,5'-metal halide-containing complexes, [MX2(bis(RfCH2OCH2)-2,2'-bpy)] [M = Pd or Pt; X = Cl or Br]. All of these ligands and metal complexes were fully characterized by multi-nuclei NMR (H-1, F-19 and C-13) and FTIR spectroscopy and mass spectrometry (GC/MS, EI and CI, or FAB). Additionally, single crystals of the Pd and Pt complexes with two bpy ligands were successfully obtained, and their X-ray structures are compared with their analogues. (c) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2012.02.009