Zn(N4C20H10-2,9-diphenyl-1,10-phenanthroline)(2-methyl-1H-imidazole) | 198889-67-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: Zn(N4C20H10-2,9-diphenyl-1,10-phenanthroline)(2-methyl-1H-imidazole)
• CAS: 198889-67-7
• 化学式: C₆₀H₃₈N₈Zn
• 分子量: 936.405
• InChiKey: RDIOJYGONPLGTE-HJDUCPGJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-甲基咪唑 、 以 1,2-二氯乙烷 为溶剂， 生成 Zn(N4C20H10-2,9-diphenyl-1,10-phenanthroline)(2-methyl-1H-imidazole)
  参考文献：
  名称：

  Recognition of Imidazoles by Strapped Zinc(II) Porphyrin Receptors:  Insight into the Induced-Fit Mechanism

  摘要：

  Imidazole-porphyrin coordination has become an important tool in the design of self-assembled materials. A combination of spectrophotometric and stopped-flow techniques has been used to gain insight into the control of imidazole binding in the distal pocket of phenanthroline-strapped porphyrins. The binding studies of a variety of imidazole substrates in combination with both hindered and accessible receptors have permitted the determination of the thermodynamic and kinetic parameters associated with the imidazole binding.

  DOI：

  10.1021/ic701590x

文献信息

• Molecular Tools for the Self-Assembly of Bisporphyrin Photodyads: A Comprehensive Physicochemical and Photophysical Study
  作者：Jérémy Brandel、Ali Trabolsi、Hassan Traboulsi、Frédéric Melin、Matthieu Koepf、Jennifer A. Wytko、Mourad Elhabiri、Jean Weiss、Anne-Marie Albrecht-Gary

  DOI：10.1021/ic802407x

  日期：2009.4.20

  Accessible and hindered phenanthroline-strapped Zn(II) porphyrin receptors exhibited suitable topography tailored to strongly and selectively bind N-1-unsubstituted imidazoles and imidazoles appended to free-base porphyrins. Distal binding was clearly driven by the formation of strong bifurcated hydrogen bonds with the phenanthroline unit of the receptors. An extensive physicochemical study emphasized the influence of bulkiness of the substrate and of the porphyrin receptor on the binding and self-assembly mechanism. Knowledge of the corresponding spectroscopic, thermodynamic, and kinetic data were of fundamental importance to elucidate and to model the photoinduced properties which occur within the self-assembled porphyrin dyads.