Li2Co2(pivalate)6(2,4-lutidine)2 | 1266239-38-6

• 英文名称: Li2Co2(pivalate)6(2,4-lutidine)2
• CAS: 1266239-38-6
• 化学式: C₄₄H₇₂Co₂Li₂N₂O₁₂
• 分子量: 952.93
• InChiKey: ATPFMCQUXJDZNY-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Li2Co2(pivalate)6(2,4-lutidine)2 以 neat (no solvent) 为溶剂， 生成 cobalt(II) oxide 、 lithium oxide
  参考文献：
  名称：

  Synthesis and characterization of Li(I)–M(II) (M = Co, Ni) heterometallic complexes as molecular precursors for LiMO2

  摘要：

  Lithium-containing heterometallic complexes with cobalt (Li2Co2(Piv)(6)(2,4-Lut)(2) (2, Piv is the pivalate anion) and Li2CO2(O2CCH2Bu)(6)(2,4-Lut)(2) (3)) and with nickel (Li2Ni2(Piv)(6)(DME)2 (4) and Li2Ni2(Piv)(6) (2,2'-bpy)(2) (5)) were synthesized. The structures of the complexes were established by X-ray diffraction. The magnetic properties of complexes 2 and 4 were studied. The thermal behavior of compounds 2, 3, and 5 was investigated. It was shown that the compounds under study can be used as molecular precursors for the synthesis of lithium cobaltate and nickelate. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.09.040
• 作为产物：
  描述：

  Co2(pivalate)4(2,4-lutidine)2 、 lithium pivalate 以 四氢呋喃 为溶剂， 以95%的产率得到Li2Co2(pivalate)6(2,4-lutidine)2
  参考文献：
  名称：

  Synthesis and characterization of Li(I)–M(II) (M = Co, Ni) heterometallic complexes as molecular precursors for LiMO2

  摘要：

  Lithium-containing heterometallic complexes with cobalt (Li2Co2(Piv)(6)(2,4-Lut)(2) (2, Piv is the pivalate anion) and Li2CO2(O2CCH2Bu)(6)(2,4-Lut)(2) (3)) and with nickel (Li2Ni2(Piv)(6)(DME)2 (4) and Li2Ni2(Piv)(6) (2,2'-bpy)(2) (5)) were synthesized. The structures of the complexes were established by X-ray diffraction. The magnetic properties of complexes 2 and 4 were studied. The thermal behavior of compounds 2, 3, and 5 was investigated. It was shown that the compounds under study can be used as molecular precursors for the synthesis of lithium cobaltate and nickelate. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.09.040