| 445290-74-4

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• CAS: 445290-74-4
• 化学式: C₂₁H₃₂N₂Pt
• 分子量: 507.578
• InChiKey: PNTVZTUXHMGFCP-KAFKVMRASA-N

反应信息

• 作为产物：
  描述：

  苯基锂 、 N,N'-di-cyclohexyl-1,4-diazabuta-1,3-diene 、 trans-[PtCl(Me)(SMe2)2] 以 乙醚 为溶剂， 生成
  参考文献：
  名称：

  Structural and Mechanistic Investigations of the Oxidation of Dimethylplatinum(II) Complexes by Dioxygen

  摘要：

  The oxidation of (tmeda)Pt-II(CH3)(2) (1, tmeda = N,N,N',N'-tetramethylethylenediamine) to (tmeda)Pt-IV(OH)(OCH3)(CH3)(2) (3) by dioxygen in methanol proceeds via a two-step mechanism. The initial reaction between (tmeda)Pt(CH3)(2) and dioxygen yields a hydroperoxoplatinum(IV) intermediate, (tmeda)Pt(OOH)(OCH3)(CH3)(2) (2), which reacts with a second equivalent of (tmeda)Pt(CH3)(2) to afford the final product 3. Both 2 and 3 have been fully characterized, including X-ray crystallographic structure determinations. The effect of ligand variation on the oxidation of several dimethylplatinum (11) complexes by 2 as well as by dioxygen has been examined.

  DOI：

  10.1021/ic0112903