| 88005-81-6

• CAS: 88005-81-6
• 化学式: Br₃Cu*C₂₄H₂₀P
• 分子量: 642.655
• InChiKey: GYUSQXISHOSRSF-UHFFFAOYSA-K

反应信息

• 作为反应物：
  描述：

  、 氯苯 、 (1,4-dioxane-2,3-diyldithio)ethylenedithiotetrathiafulvalene 以 乙醇 、 氯苯 为溶剂， 生成 β-((1,4-dioxanediyl-2,3-dithio)ethylenedithiotetrathiafulvalene)4CuBr4*chlorobenzene
  参考文献：
  名称：

  Crystal structure of radical-cation salt β-(DOET)4CuBr4·PhCl

  摘要：

  A new radical-cation salt beta-(DOET)(4)CuBr4 center dot PhCl(DOET = (1,4-dioxanediyl-2,3-dithio) ethylene-dithiotetrathiafulvalene) is synthesized by electrocrystallization in the dc mode (I = 0.12 mu A), and its structure is studied. In the structure of the salt, the DOET radical cations are packed in layers parallel to ab. The average charge on DOET is equal to +0.5. The dioxane rings and ethylene groups of DOET, the tetrahedral CuBr42 -anion, and the chlorobenzene molecules are each disordered over two positions with a 50% probability, and the chlorine atoms of chlorobenzene are disordered over four positions with a 25% probability. The salt has semiconducting properties (E-a = 55 meV).

  DOI：

  10.1134/s0036023606120084