(3Ξ:3'Ξ)-3,3'-dipalmitoyloxy-4,4'-didehydro-all-trans-β-carotene | 3484-58-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (3Ξ:3'Ξ)-3,3'-dipalmitoyloxy-4,4'-didehydro-all-trans-β-carotene
• 英文别名: Di-O-palmitoyl-eschscholtzxanthin；(3Ξ:3'Ξ)-3,3'-Dipalmitoyloxy-4,4'-didehydro-all-trans-β-carotin；3,7,12,16-Tetramethyl-1,18-bis-((Ξ)-4-palmitoyloxy-2,2,6-trimethyl-cyclohexen-(5)-yliden-(seqcis))-octadecaoctaen-(2t,4t,6t,8t,10t,12t,14t,16t)
• CAS: 3484-58-0
• 化学式: C₇₂H₁₁₄O₄
• 分子量: 1043.69
• InChiKey: HAKNWJJZXZQHFD-IKFAGBMKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  22.39
• 重原子数：
  76.0
• 可旋转键数：
  39.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  52.6
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  (3Ξ:3'Ξ)-3,3'-dipalmitoyloxy-4,4'-didehydro-all-trans-β-carotene 在 氢氧化钾 、 苯 作用下， 生成 eschscholtzxanthin
  参考文献：
  名称：

  Hallucinogens and Redemption

  摘要：

  This article examines drug substitution with regard to hallucinogens (ayahuasca, ibogaine, peyote and LSD) set within the concept of redemption. The model examines both religious and secular approaches to the contemporary use of hallucinogens in drug substitution, both by scientists and in religious settings worldwide. The redemptive model posits that the proper use of one psychoactive substance within a spiritual or clinical context helps to free an individual from the adverse effects of their addiction to another substance and thus restores them as functioning members of their community or group. Data is drawn from the U.S., Brazil, Peru, and West Africa. Two principle mechanisms for this are proposed: the psychological mechanism of suggestibility is examined in terms of the individual reaching abstinence goals from addictive substances such as alcohol and opiates. Neurophysiological and neurochemical mechanisms to understand the efficacy of such substitution are highlighted from ongoing research on hallucinogens. Research by two of the authors with the Unaio do Vegetal (UDV) Church in Brazil is examined in terms of the model.

  DOI：

  10.1080/02791072.2002.10399960
• 作为产物：
  描述：

  (+)-3,7,12,16-Tetramethyl-1,18-bis-((Ξ)-4-hydroxy-2,2,6-trimethyl-cyclohexen-(5)-yliden-(seqcis))-octadecaoctaen-(2t,4t,6t,8t,10t,12t,14t,16t) 、 棕榈酰氯 在 吡啶 作用下， 生成 (3Ξ:3'Ξ)-3,3'-dipalmitoyloxy-4,4'-didehydro-all-trans-β-carotene
  参考文献：
  名称：

  Strain, Journal of Biological Chemistry, 1938, vol. 123, p. 425,434

  摘要：

  DOI：