顺-9-十四碳烯乙酸酯 | 16725-53-4

• 物质功能分类: 化学试剂 - 有机试剂 - 酯类
• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 顺-9-十四碳烯乙酸酯
• 中文别名: 醋酸(Z)-9-十四烯酯；顺-9-十四碳烯-1-醇乙酸酯
• 英文名称: (Z)-9-tetradecen-1-yl acetate
• 英文别名: (Z)-9-tetradecenyl acetate；cis-9-tetradecenyl acetate；(Z)-tetradec-9-en-1-yl acetate；[(Z)-tetradec-9-enyl] acetate
• CAS: 16725-53-4
• 化学式: C₁₆H₃₀O₂
• 分子量: 254.413
• InChiKey: XXPBOEBNDHAAQH-SREVYHEPSA-N

物化性质

• 熔点：
  25°C (estimate)
• 沸点：
  135 °C (0.5 mmHg)
• 密度：
  0.87
• 闪点：
  98.5±20.4℃
• LogP：
  6.490 (est)
• 保留指数：
  1790;1783.3

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 安全说明：
  S24/25
• 海关编码：
  2915390090
• 危险性防范说明：
  P501,P270,P264,P280,P302+P352,P337+P313,P305+P351+P338,P362+P364,P332+P313,P301+P312+P330
• 危险性描述：
  H302,H315,H319
• 储存条件：
  -20°C

SDS

Name:	Cis-9-Tetradecenyl Acetate 95% Material Safety Data Sheet
Synonym:	Myristoleyl acetate; Z-9-TDA
CAS:	16725-53-4

Section 1 - Chemical Product MSDS Name:Cis-9-Tetradecenyl Acetate 95% Material Safety Data Sheet
Synonym:Myristoleyl acetate; Z-9-TDA

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
16725-53-4	cis-9-Tetradecenyl acetate	95%	240-780-1

Hazard Symbols: None Listed.
Risk Phrases: None Listed.

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.
Chronic:
No information found.

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Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If inhaled, remove to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 16725-53-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Clear liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 135 deg C @0.5mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 0.870
Molecular Formula: C16H30O2
Molecular Weight: 254

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 16725-53-4: XB9130000 LD50/LC50:
CAS# 16725-53-4: Oral, rat: LD50 = >5000 mg/kg.
Carcinogenicity:
cis-9-Tetradecenyl acetate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 16725-53-4: No information available.
Canada
CAS# 16725-53-4 is listed on Canada's NDSL List.
CAS# 16725-53-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 16725-53-4 is listed on the TSCA inventory.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  顺-9-十四碳烯乙酸酯 在 sodium hydroxide 作用下， 以 甲醇 为溶剂， 生成 顺-9-十四碳烯醇
  参考文献：
  名称：

  信息素VII。1-取代的（Z）-9-烯烃的合成

  摘要：

  描述了通过立体选择性Wittig反应制备1-取代的（Z）-9烯烃的一般方法。它能够合成信息素并对其结构进行系统修饰。讨论了以此方式获得的某些化合物的生理有效性。

  DOI：

  10.1002/cber.19751081120
• 作为产物：
  描述：

  1-溴-8-(四氢吡喃氧基)辛烷 在 吡啶 、 sodium tetrahydroborate 、 正丁基锂 、 乙醇 、 氢气 、 nickel diacetate 、 4-甲基苯磺酸吡啶 、 乙二胺 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 38.5h， 生成 顺-9-十四碳烯乙酸酯
  参考文献：
  名称：

  열대거세미나방의 성페로몬인 (Z)-9-테트라데세닐 아세테이트의 제조방법

  摘要：

  本发明涉及使用1,8-氧杂二醇或1,8-二溴辛烷作为起始材料，制备热带飞机姬蜂性信息素主要成分之一（Z）-9-顺式-四十四碳烯酸乙酯的方法。根据本发明的方法，可以通过使用廉价的起始材料1,8-氧杂二醇或1,8-二溴辛烷，以低成本制备热带飞机姬蜂性信息素的主要成分（Z）-9-顺式-四十四碳烯酸乙酯，从而降低信息素的供应成本，以较低价格供应给农户。此外，通过利用其诱引热带飞机姬蜂并将其捕获在诱捕器中，可以有效收集害虫（热带飞机姬蜂）的发生成.isDefined、时机、密度等监测信息，从而在减少杀虫剂滥用的同时，实现对热带飞机姬蜂的防治。

  公开号：

  KR20230118397A

文献信息

• [EN] MICROBIOCIDAL OXADIAZOLE DERIVATIVES<br/>[FR] DÉRIVÉS D'OXADIAZOLE MICROBIOCIDES
  申请人：SYNGENTA PARTICIPATIONS AG

  公开号：WO2017157962A1

  公开（公告）日：2017-09-21

  Compounds of the formula (I) wherein the substituents are as defined in claim 1, useful as a pesticides, especially fungicides.

  式(I)的化合物，其中取代基如权利要求1所定义，作为杀虫剂特别是杀菌剂有用。
• [EN] INSECTICIDAL TRIAZINONE DERIVATIVES<br/>[FR] DÉRIVÉS DE TRIAZINONE INSECTICIDES
  申请人：SYNGENTA PARTICIPATIONS AG

  公开号：WO2013079350A1

  公开（公告）日：2013-06-06

  Compounds of the formula (I) or (I'), wherein the substituents are as defined in claim 1, are useful as pesticides.

  式(I)或(I')的化合物，其中取代基如权利要求1所定义的那样，可用作杀虫剂。
• Novel insecticides
  申请人：Syngenta Participations AG

  公开号：EP2540718A1

  公开（公告）日：2013-01-02

  Compounds of formula I wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts and all stereoisomers and tautomeric forms of the compounds of formula I can be used as insecticides and can be prepared in a manner known per se.

  式I的化合物 其中取代基如权利要求1所定义，并且式I化合物的农药可接受盐以及所有立体异构体和互变异构形式可用作杀虫剂，并且可以按照已知的方法制备。
• [EN] MICROBIOCIDAL QUINOLINE (THIO)CARBOXAMIDE DERIVATIVES<br/>[FR] DÉRIVÉS MICROBIOCIDES DE QUINOLÉINE (THIO)CARBOXAMIDE
  申请人：SYNGENTA PARTICIPATIONS AG

  公开号：WO2019053010A1

  公开（公告）日：2019-03-21

  Compounds of the formula (I) wherein the subsitiuents are as defined in claim 1. Furthermore, the present invention relates to agrochemical compositions which comprise compounds of formula (I), to preparation of these compositions, and to the use of the compounds or compositions in agriculture or horticulture for combating, preventing or controlling infestation of plants, harvested food crops, seeds or non-living materials by phytopathogenic microorganisms, in particular fungi.

  式(I)中的化合物，其中取代基如权利要求1所定义。此外，本发明涉及包括式(I)化合物的农药组合物，制备这些组合物以及在农业或园艺中使用这些化合物或组合物来对抗、预防或控制植物、收获的农作物、种子或非生物材料受植物病原微生物，特别是真菌的侵害。
• [EN] SUBSTITUTED [1,2,4]TRIAZOLE AND IMIDAZOLE COMPOUNDS<br/>[FR] COMPOSÉS IMIDAZOLE ET TRIAZOLE SUBSTITUÉS EN [1,2,4]
  申请人：BASF SE

  公开号：WO2014095655A1

  公开（公告）日：2014-06-26

  The present invention relates to compounds of the formula (I) wherein the substituents are defined in the description and claims, their preparation and uses of the compounds I.

  本发明涉及公式（I）中取代基的化合物，其中取代基在描述和权利要求中定义，以及化合物I的制备和用途。

表征谱图