| 545445-87-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• CAS: 545445-87-2
• 化学式: C₄₉H₆₇NO₃Ti
• 分子量: 765.956
• InChiKey: IZKLGIQYVFSXBO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  6,6′-((((tetrahydrofuran-2-yl)methyl)azanediyl)bis(methylene))bis(2,4-di-tert-butylphenol) 、 tetrabenzyl titanium 以 甲苯 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Group IV complexes of an amine bis(phenolate) ligand featuring a THF sidearm donor: from highly active to living polymerization catalysts of 1-hexene

  摘要：

  A new amine bis(phenolate) ligand bearing a THF donor on a sidearm and several dialkyl complexes of the group IV triad are introduced. The crystal structures of a zirconium dibenzyl complex and a titanium dibenzyl complex were solved, and revealed a strong binding of the oxygen donor of the THF group to the metal center. Upon activation with tris(pentafluorophenyl)borane the zirconium and the hafnium dibenzyl complexes lead to highly active 1-hexene polymerization catalysts. In comparison, titanium complexes (a dibenzyl complex and a dimethyl complex) lead to slower but living polymerization of 1-hexene at room temperature. Polymerization of neat 1-hexene under high dilution conditions was found to be living for an exceptionally long time of 6 days, leading to poly(1-hexene) of M-w = 816000 and PDI = 1.09. A block copolymerization of 1-hexene and I-octene at room temperature could be obtained using the titanium catalysts. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01306-3