1-vinyl-1-methyl-3-(4',8'-dimethyl-3'E,7'-nonadienyl)cyclohex-3-ene | 134600-25-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 1-vinyl-1-methyl-3-(4',8'-dimethyl-3'E,7'-nonadienyl)cyclohex-3-ene
• CAS: 134600-25-2
• 化学式: C₂₀H₃₂
• 分子量: 272.474
• InChiKey: JEXVZDVNFKTALP-LDADJPATSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.76
• 重原子数：
  20.0
• 可旋转键数：
  7.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  1-vinyl-1-methyl-3-(4',8'-dimethyl-3'E,7'-nonadienyl)cyclohex-3-ene 在 sodium hydroxide 、 9-borabicyclononane 、 双氧水 作用下， 生成 1-(2-hydroxyethyl)-1-methyl-3-(4',8'-dimethyl-3'E,7'-nonadienyl)cyclohex-3-ene
  参考文献：
  名称：

  3-Substituted 1-vinyl-1-methylcyclohex-3-enes ? Precursors of tricyclic diterpenoids of the pimarane/rosane group

  摘要：

  The synthesis of 1-vinyl-1-methyl-3-chloromethylcyclohex-3-ene from 3-vinyl-3-methylcyclohexanone and the corresponding exomethylene derivative has been optimized and related allylsulfones prepared. By a standard combination of these compounds with the appropriate (cyclo)geranyl block synthones a series of regular functionalized diterpenoids has been prepared which are considered as likely precursors of the natural compounds indicated in the title.

  DOI：

  10.1007/bf00958567
• 作为产物：
  描述：

  geranyl phenyl sulfone 、 cis/trans-5-vinyl-5-methyloxaspiro<2.5>octane 在 lithium 作用下， 生成 1-vinyl-1-methyl-3-(4',8'-dimethyl-3'E,7'-nonadienyl)cyclohex-3-ene
  参考文献：
  名称：

  3-Substituted 1-vinyl-1-methylcyclohex-3-enes ? Precursors of tricyclic diterpenoids of the pimarane/rosane group

  摘要：

  The synthesis of 1-vinyl-1-methyl-3-chloromethylcyclohex-3-ene from 3-vinyl-3-methylcyclohexanone and the corresponding exomethylene derivative has been optimized and related allylsulfones prepared. By a standard combination of these compounds with the appropriate (cyclo)geranyl block synthones a series of regular functionalized diterpenoids has been prepared which are considered as likely precursors of the natural compounds indicated in the title.

  DOI：

  10.1007/bf00958567