10,10'-dimethyldotriacont-1,1'-diene | 201670-74-8

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 10,10'-dimethyldotriacont-1,1'-diene
• 英文别名: 10,23-dimethyldotriaconta-1,31-diene
• CAS: 201670-74-8
• 化学式: C₃₄H₆₆
• 分子量: 474.898
• InChiKey: PQHTUAICCTUXDX-UHFFFAOYSA-N

物化性质

• 沸点：
  532.2±17.0 °C(Predicted)
• 密度：
  0.817±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  12.77
• 重原子数：
  34.0
• 可旋转键数：
  29.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  10,10'-dimethyldotriacont-1,1'-diene 在 sodium hydroxide 、 双氧水 、 二(3-甲基丁烷-2-基)硼烷 、 三乙胺 作用下， 反应 79.0h， 生成 (+/-)10,10'-dimethyldotriacont-1,1'-diyl-bis[2-(trimethylammonio)ethyl phosphate]
  参考文献：
  名称：

  Simple and high yield synthesis of (±)10,10′-dimethyl-dotriacontan-1,1′-diol as a building block for branched bola compounds. Preparation of (±)10,10′-dimethyl-dotriaconta-1,1′-diyl-bis[2-(trimethylammonio)ethyl phosphate] and the corresponding unbranched equivalent

  摘要：

  The synthesis of a specially methyl branched bipolar hydrocarbon chain is described by alkylation of 1,12-dibro-mododecane with two equivalents of the dianion of undec-10-enoic acid. The subsequent transformation includes the reduction of the carboxyl groups to methyl branches and the hydroboration of the terminal olefines. The resulting 1,32 diol is suitable for phosphorylation in order to form the corresponding 1,1'bis-phosphocholine. (C) 1997 Elsevier Science Ireland Ltd.

  DOI：

  10.1016/s0009-3084(97)00073-x
• 作为产物：
  描述：

  1,12-二溴十二烷 在 4-二甲氨基吡啶 、 lithium aluminium tetrahydride 、 正丁基锂 、 sodium hydride 、 二异丙胺 作用下， 以 乙醚 、 氯仿 为溶剂， 反应 44.0h， 生成 10,10'-dimethyldotriacont-1,1'-diene
  参考文献：
  名称：

  Simple and high yield synthesis of (±)10,10′-dimethyl-dotriacontan-1,1′-diol as a building block for branched bola compounds. Preparation of (±)10,10′-dimethyl-dotriaconta-1,1′-diyl-bis[2-(trimethylammonio)ethyl phosphate] and the corresponding unbranched equivalent

  摘要：

  The synthesis of a specially methyl branched bipolar hydrocarbon chain is described by alkylation of 1,12-dibro-mododecane with two equivalents of the dianion of undec-10-enoic acid. The subsequent transformation includes the reduction of the carboxyl groups to methyl branches and the hydroboration of the terminal olefines. The resulting 1,32 diol is suitable for phosphorylation in order to form the corresponding 1,1'bis-phosphocholine. (C) 1997 Elsevier Science Ireland Ltd.

  DOI：

  10.1016/s0009-3084(97)00073-x