| 1443323-93-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• CAS: 1443323-93-0
• 化学式: C₄₄H₃₂CoN₆O₆
• 分子量: 799.768
• InChiKey: PNKNMWHDDSQGLJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡啶 、 cobalt(II) chloride hexahydrate 、 2-[2-(4-nitrophenyl)ethenyl]quinolin-8-ol 以 N,N-二甲基甲酰胺 、 甲醇 为溶剂， 反应 24.5h， 以83%的产率得到
  参考文献：
  名称：

  Supramolecular assembly of two two-folded helical structures based on 2-substituted 8-hydroxyquinoline complexes

  摘要：

  Based on two 2-substituted 8-hydroxyquinoline ligands containing -NO2 and -Cl, two complexes [Co(L-2)(2)(pyridine)(2)] (1) and [Cu(L-3)(2)] (2) were synthesized and characterized with single-crystal X-ray diffractions, powder X-ray diffractions (PXRD), thermal analyses (TGA) and elemental analyses (EA). In the solid state, the supramolecular structures of 1 and 2 feature two different two-folded helical chains, which were constructed by non-covalent interactions, such as pi-pi stacking, C-H...pi and C-H center dot center dot center dot O, C-Cl...pi and Cl center dot center dot center dot Cl interactions. The present research holds great promise in the development of novel functional helical structure, and may contribute to the understanding of helical organized systems in biology. (c) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2013.03.036