| 282533-65-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 282533-65-7
• 化学式: CN*C₃₅H₃₃NP₃Pt
• 分子量: 781.673
• InChiKey: XYABCWYMOUXIFD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [chloro(bis[(2-diphenylphosphino)ethyl]phenylphosphine)platinum(II)] chloride 在 potassium cyanide 作用下， 以 乙醇 、 水 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Brueggeller, Peter, Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1986, vol. 41, # 12, p. 1561 - 1564

  摘要：

  DOI：

文献信息

• Synthesis and NMR investigation of Pt(CN)2(diphosphine) and [Pt(CN)(triphosphine)]Cl complexes
  作者：György Petőcz、László Jánosi、Walter Weissensteiner、Zsolt Csók、Zoltán Berente、László Kollár

  DOI：10.1016/s0020-1693(00)00042-6

  日期：2000.5

  Pt(CN)(2)(Ph2P(CH2)(n)PPh2) (n = 2,3,4) and Pt(CN)(2)(P-1-P-2) (P-1-P-2 = 1-diphenylphosphino-2,1'-[(1-diphenylphosphino)-1,3-propanediyl]-ferrocene, 1-diphenylphosphino-2,1'-[(1-dicyclohexylphosphino)-1.3-propanediyl]-ferrocene) were synthesised by reacting potassium cyanide and the corresponding PtCl2(diphosphine) complexes. PtCl(CN)(diphosphine) complexes were identified as minor products when KCN/PtCl2(diphosphine) molar ratio was kept below 2. The use of KCN in excess resulted in the formation of K2Pt(CN)(4). [Pt(CN)(Ph2P(CH2)(2)}(2)PPh)](+) complex cation and Pt(CN)(2))(Ph2P(CH2)(2)}(2)PPh) five-coordinate covalent complex of fluxional behaviour were obtained at KCN/Pt ratio of 1 and 2, respectively. The platinum-cyano complexes were characterised by NMR spectroscopy. The direct Pt-CN bond was proved by (1)J(Pt-195,P-31), (2)J(P-31,C-13) coupling constants by using sodium cyanide-C-13 for ligand exchange reactions. (C) 2000 Elsevier Science S.A. All rights reserved.