(2S,3R,4S,5S,6R)-4-Allyloxy-2-((3aR,5R,6S,7S,7aR)-2-benzyloxy-7-hydroxy-5-hydroxymethyl-2-methyl-tetrahydro-[1,3]dioxolo[4,5-b]pyran-6-yloxy)-6-hydroxymethyl-tetrahydro-pyran-3,5-diol | 120424-67-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (2S,3R,4S,5S,6R)-4-Allyloxy-2-((3aR,5R,6S,7S,7aR)-2-benzyloxy-7-hydroxy-5-hydroxymethyl-2-methyl-tetrahydro-[1,3]dioxolo[4,5-b]pyran-6-yloxy)-6-hydroxymethyl-tetrahydro-pyran-3,5-diol
• 英文别名: (2S,3R,4S,5S,6R)-2-[[(3aR,5R,6S,7S,7aR)-7-hydroxy-5-(hydroxymethyl)-2-methyl-2-phenylmethoxy-5,6,7,7a-tetrahydro-3aH-[1,3]dioxolo[4,5-b]pyran-6-yl]oxy]-6-(hydroxymethyl)-4-prop-2-enoxyoxane-3,5-diol
• CAS: 120424-67-1
• 化学式: C₂₄H₃₄O₁₂
• 分子量: 514.527
• InChiKey: JWARJEIREPUNBW-AIFKGXPYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.9
• 重原子数：
  36
• 可旋转键数：
  10
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  166
• 氢给体数：
  5
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  (2S,3R,4S,5S,6R)-4-Allyloxy-2-((3aR,5R,6S,7S,7aR)-2-benzyloxy-7-hydroxy-5-hydroxymethyl-2-methyl-tetrahydro-[1,3]dioxolo[4,5-b]pyran-6-yloxy)-6-hydroxymethyl-tetrahydro-pyran-3,5-diol 、 溴甲苯 、 三甲基乙酰氯 生成 benzyl O-(2,4,6-tri-O-benzyl-β-D-galactopyranosyl)-(1->4)-3,6-di-O-benzyl-2-O-pivaloyl-β-D-glucopyranoside
  参考文献：
  名称：

  An efficient approach to stereoselective glycosylation of ceramide derivatives: Use of pivaloyl group as a stereocontrolling auxiliary

  摘要：

  DOI：

  10.1016/s0040-4039(00)80426-8
• 作为产物：
  描述：

  (2S,3R,4R,5R,6R)-2-[[(3aR,5R,6S,7S,7aR)-7-hydroxy-5-(hydroxymethyl)-2-methyl-2-phenylmethoxy-5,6,7,7a-tetrahydro-3aH-[1,3]dioxolo[4,5-b]pyran-6-yl]oxy]-6-(hydroxymethyl)oxane-3,4,5-triol 、 3-溴丙烯 生成 (2S,3R,4S,5S,6R)-4-Allyloxy-2-((3aR,5R,6S,7S,7aR)-2-benzyloxy-7-hydroxy-5-hydroxymethyl-2-methyl-tetrahydro-[1,3]dioxolo[4,5-b]pyran-6-yloxy)-6-hydroxymethyl-tetrahydro-pyran-3,5-diol
  参考文献：
  名称：

  SATO, SUSUMU;NUNOMURA, SHIGEKI;NAKANO, TAKAHISA;ITO, YUKISHIGE;OGAWA, TOM+, TETRAHEDRON LETT., 29,(1988) N 33, C. 4097-4100

  摘要：

  DOI：