pyrocatechol; lead (II)-pyrocatecholate | 138711-52-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: pyrocatechol; lead (II)-pyrocatecholate
• 英文别名: Brenzcatechin; Blei(II)-brenzcatechinat；Brenzcatechin; Blei(II)-Verbindung；Lead(II) catecholate；1,3,2λ2-benzodioxaplumbole
• CAS: 138711-52-1
• 化学式: C₆H₄O₂*Pb
• 分子量: 315.297
• InChiKey: BQJDLUVVZBAKQD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  0.99
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  碘 、 pyrocatechol; lead (II)-pyrocatecholate 以 乙腈 为溶剂， 以81%的产率得到
  参考文献：
  名称：

  Synthetic routes to lead(II) derivatives of aromatic 1,2-diols and orthoquinones

  摘要：

  Complexes of lead(II) of the type Pb(O2R) where R is a substituted aromatic group, can be prepared by the direct electrochemical oxidation of a lead anode in a non-aqueous solution of the appropriate substituted catechol, R(OH)(2). The products, which are colourless, air-stable, insoluble materials, and presumably cross-linked in the solid state, can be oxidised to the corresponding lead(IV) derivatives by iodine or tetrahalogeno-o-quinones. The direct reaction of elemental lead with an o-quinone in refluxing hexane or toluene yielded identifiable products in only two cases; with 2,5-tert-butyl-1,2-benzoquinone, the corresponding lead(II) catecholate was obtained, while with phenanthrenequinone the semiquitionate Pb(PSQ(.))(2) was isolated. These latter reactions are shown by electron spin resonance spectroscopy to proceed via free radical intermediates, and the spectra are analysed to give information on the species present in the reaction media. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00057-4
• 作为产物：
  描述：

  lead(IV) tetraacetate 、 邻苯二酚 生成 pyrocatechol; lead (II)-pyrocatecholate
  参考文献：
  名称：

  Zwenger, Justus Liebigs Annalen der Chemie, 1841, vol. 37, p. 332

  摘要：

  DOI：

文献信息

• Wagner, Justus Liebigs Annalen der Chemie, 1851, vol. 80, p. 317
  作者：Wagner

  DOI：——

  日期：——
• Wagner, Journal fur praktische Chemie (Leipzig 1954), 1851, vol. <1> 52, p. 452
  作者：Wagner

  DOI：——

  日期：——