Tetracyclo<6,2,1,1^3,6,0^2,7>dodec-4,5-ylendimethanol | 37501-78-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: Tetracyclo<6,2,1,1^3,6,0^2,7>dodec-4,5-ylendimethanol
• 英文别名: [5-(Hydroxymethyl)-4-tetracyclo[6.2.1.13,6.02,7]dodecanyl]methanol
• CAS: 37501-78-3
• 化学式: C₁₄H₂₂O₂
• 分子量: 222.327
• InChiKey: WHKRIYVKCFZWRS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

文献信息

• Polycarbonate or polyestercarbonate resins
  申请人：KURARAY CO., LTD.

  公开号：EP0357073A2

  公开（公告）日：1990-03-07

  Provided are novel polycarbonate or polyestercarbonate resins having excellent performances including excellent transparency and thermal resistance, very small warping or deformation caused by water absorption, and the like.

  所提供的新型聚碳酸酯或聚酯碳酸酯树脂具有优异的性能，包括极佳的透明度和耐热性、极小的翘曲或吸水变形等。
• POLYESTER RESIN
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP3351577A1

  公开（公告）日：2018-07-25

  A polyester resin mainly having a diol constitutional unit and a dicarboxylic acid constitutional unit, wherein 20 to 100 mol% of the diol constitutional unit is a constitutional unit derived from a diol having a dinorbornane ring represented by the following formula (i); a glass transition temperature is 90°C or higher; an amount of heat of a crystallization exothermic peak in temperature drop is 5 J/g or less; and an YI value as measured by a reflection method according to JIS K 7103 is 10 or less: wherein R is H, CH3, or C2H5.

  一种主要具有二元醇构型单元和二羧酸构型单元的聚酯树脂，其中 20 至 100 摩尔%的二元醇结构单元是由具有二降冰片烷环的二元醇衍生的结构单元，二降冰片烷环由下式(i)表示； 玻璃化温度为 90°C 或更高；结晶放热峰的温降热量为 5 焦耳/克或更低；以及 根据 JIS K 7103 的反射法测得的 YI 值为 10 或以下： 其中 R 为 H、CH3 或 C2H5。
• Polycarbonate resin and optical lens
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US10605956B2

  公开（公告）日：2020-03-31

  The present invention addresses the problem of providing a resin having a high Abbe number and a small difference in hygroscopic expansion coefficient with respect to a polycarbonate resin having a low Abbe number and a high refractive index. The above problem can be solved by a polycarbonate resin including structural units represented by general formula (1). In general formula (1), R represents H, CH3, or C2H5.

  本发明要解决的问题是提供一种阿贝数高且吸湿膨胀系数与阿贝数低且折射率高的聚碳酸酯树脂相差较小的树脂。包含通式（1）表示的结构单元的聚碳酸酯树脂可以解决上述问题。在通式（1）中，R 代表 H、CH3 或 C2H5。
• Polyester resin
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US10889684B2

  公开（公告）日：2021-01-12

  A polyester resin having a diol constitutional unit and a dicarboxylic acid constitutional unit, wherein 20 to 100 mol % of the diol constitutional unit is a constitutional unit derived from a diol having a dinorbornane ring; a glass transition temperature of the polyester resin is 90° C. or higher; an amount of heat of a crystallization exothermic peak in temperature drop of the polyester resin is 5 J/g or less; and a yellow index (YI) value as measured by a reflection method according to JIS K 7103 is 10 or less.

  一种具有二元醇组成单元和二羧酸组成单元的聚酯树脂，其中 20 至 100 摩尔%的二元醇组成单元是由具有二降冰片烷环的二元醇衍生的组成单元；聚酯树脂的玻璃化温度为 90°C 或更高；聚酯树脂温降中结晶放热峰的热量为 5 焦耳/克或更低；根据 JIS K 7103 的反射法测得的黄色指数（YI）值为 10 或更低。
• Functional polyester polymer and production process thereof
  申请人：——

  公开号：US20010021766A1

  公开（公告）日：2001-09-13

  A polyester polymer is a condensation product of a diol component and a dicarboxylic acid component, and the diol component (i) includes at least one tricyclo[5.2.1.0 2,6 ]decanedimethanol represented by the following formula (1): 1 wherein two hydroxymethyl groups are bound to carbon atoms constituting tricyclo[5.2.1.0 2,6 ]decane ring and wherein each of carbon atoms constituting the ring may have at least one additional substituent; or (ii) the dicarboxylic acid component includes at least one tricyclo[5.2.1.0 2,6 ]decanedicarboxylic acid represented by the following formula (2): 2 wherein two carboxyl groups are bound to carbon atoms constituting tricyclo[5.2.1.0 2,6 ]decane ring and wherein each of carbon atoms constituting the ring may have at least one additional substituent. The polyester polymer has an excellent formability in addition to a high heat resistance, low water absorption property, and satisfactory optical characteristics.

  聚酯聚合物是二元醇组分和二羧酸组分的缩合产物，二元醇组分 (i) 包括至少一种三环[5.2.1.0 2,6 ]癸烷二甲醇，由下式（1）表示： 1 其中两个羟甲基与构成三环[5.2.1.0 2,6]癸烷二甲醇的碳原子结合。 2,6 其中两个羟甲基与构成三环[5.2.1.0 2，6]癸烷环的碳原子结合，而构成该环的每个碳原子可具有至少一个附加取代基；或 (ii) 二羧酸组分包括至少一个三环[5.2.1.0 2，6]癸烷环的碳原子。 2,6 ]decanedicarboxylic acid，由下式（2）代表： 2 其中两个羧基与构成三环[5.2.1.0 的碳原子结合 2,6 其中两个羧基与构成三环[5.2.1.0 2，6]癸烷环的碳原子结合，而构成该环的每个碳原子可具有至少一个附加取代基。这种聚酯聚合物具有优异的成型性、高耐热性、低吸水性和令人满意的光学特性。