4-硝基苯并[b]噻吩 | 10133-34-3

• 物质功能分类: 有机原料 - 杂环化合物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻吩类
• 中文名称: 4-硝基苯并[b]噻吩
• 英文名称: 4-nitrobenzene[b]thiophene
• 英文别名: 4-nitro-benzo[b]thiophene；4-Nitro-benzo[b]thiophen；4-Nitro-benzothiophen；4-Nitro-benzthiophen；4-Nitro-thianaphthen；4-Nitro-thionaphthen；4-Nitrobenzo[b]thiophene；4-nitro-1-benzothiophene
• CAS: 10133-34-3
• 化学式: C₈H₅NO₂S
• mdl: MFCD08695317
• 分子量: 179.199
• InChiKey: RQVCNKOGKIBIEV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.1
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2934999090

反应信息

• 作为反应物：
  描述：

  4-硝基苯并[b]噻吩 在 5%-palladium/activated carbon 、 氢气 、 三乙胺 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 20.0~50.0 ℃ 、300.01 kPa 条件下， 反应 24.5h， 生成 依匹唑派
  参考文献：
  名称：

  一种用于合成依匹哌唑的制备方法

  摘要：

  本发明提供了一种用于合成依匹哌唑的制备方法，具体步骤为：以4‑硝基苯[b]噻吩为原料氢化反应合成中间体化合物(Ⅱ)，以7‑羟基‑1H‑喹啉‑2‑酮为原料第一步反应合成得到化合物(Ⅲ)，第二步得到中间体化合物(Ⅳ)。然后中间体化合物(Ⅱ)和中间体化合物(Ⅳ)缩合制得目标化合物(Ⅰ)，即依匹哌唑。本发明整个合成路线的原料均易得，操作简便，操作成本低，绿色环保，且各步骤反应的收率高，十分适合于工业化生产，具有极强的工业应用价值。

  公开号：

  CN106831739A
• 作为产物：
  描述：

  4-nitro-benzo[b]thiophen-5-ylamine 在 硫酸 、 sodium nitrite 作用下， 生成 4-硝基苯并[b]噻吩
  参考文献：
  名称：

  Benzothiophene Chemistry. VII. Substitution Reactions of 5-Hydroxy- and 5-Aminobenzothiophene Derivatives

  摘要：

  DOI：

  10.1021/ja01627a048

文献信息

• FLUORINE-FREE FUSED RING HETEROAROMATIC PHOTOACID GENERATORS AND RESIST COMPOSITIONS CONTAINING THE SAME
  申请人：Liu Sen

  公开号：US20130011786A1

  公开（公告）日：2013-01-10

  The present invention relates to a fluorine-free photoacid generator (PAG) and a photoresist composition containing the same. The PAG is characterized by the presence of an onium cationic component and a fluorine-free fused ring heteroaromatic sulfonate anionic component containing one or more electron withdrawing substituents. The onium cationic component of the PAG is preferably a sulfonium or an iodonium cation. The photoresist composition further contains an acid sensitive imaging polymer. The photoresist composition is especially useful for forming material patterns on a semiconductor substrate using 193 nm (ArF) lithography.

  本发明涉及一种无氟光酸发生剂（PAG）和含有该PAG的光刻胶组合物。该PAG的特点是具有一个onium阳离子组分和一个不含氟的融合环杂芳基磺酸盐阴离子组分，其中包含一个或多个电子吸引取代基。该PAG的onium阳离子组分优选为烷基磺酸盐或碘酸盐阳离子。该光刻胶组合物还包含一种酸敏感成像聚合物。该光刻胶组合物在使用193 nm（ArF）光刻术在半导体基板上形成材料图案方面特别有用。
• Benzo[b]thiophen derivatives. Part IX. Nitration of benzo[b]thiophen and the isomeric nitrobenzo[b]thiophens
  作者：K. J. Armstrong、M. Martin-Smith、N. M. D. Brown、G. C. Brophy、S. Sternhell

  DOI：10.1039/j39690001766

  日期：——

  3-nitrobenzo[b]thiophen and in terms of the influence of peri interaction in the 3,4-dinitro-compound. The 1H n.m.r. spectra of 3,4-, 3,5-, 3,6-, and 3,7-dinitrobenzo[b]thiophens, the structures of which are confirmed by chemical means, and the 1H n.m.r. spectra of the six isomeric mononitrobenzo[b]thiophens are recorded. Nitration of benzo[b]-thiophen is shown to give some 7-nitrobenzo[b]thiophen and reassignment

  对3-硝基苯并[ b ]噻吩进行硝化的研究证实，在高温下，它对冰醋酸中的发烟硝酸缺乏反应性，但表明在苯环中进行处理时，苯环的所有位置都会发生取代。用浓硫酸中的一摩尔比例的硝酸钾或硝酸，乙酸和乙酸酐的混合物进行冷却。替代的顺序所观察到的偏好6> 5> 4> 7位中的电子密度计算为3-硝基苯并[方面讨论b ]噻吩和中的影响方面围在3,4-二硝基相互作用-化合物。3,4-，3,5-，3,6-和3,7-二硝基苯并[的1 H nmr光谱[b ]噻吩，通过化学方法确定其结构，并记录六个异构的单硝基苯并[ b ]噻吩的1 H nmr光谱。苯并[硝化b ] -噻吩被示出，得到一些7-硝基苯并[ b ]噻吩和结构的重新分配为3,4,6- trinitrobenzo [ b ]噻吩被预先正确特征的化合物制成。记录了六个异构的单硝基苯并[ b ]噻吩的Glc保留时间。
• Composition containing carbon nanotubes having coating thereof and process for producing them
  申请人：Saitoh Takashi

  公开号：US20060052509A1

  公开（公告）日：2006-03-09

  The object of the present invention is to provide a carbon nanotube composition that does not impair the characteristics of the carbon nanotubes itself, allows the carbon nanotubes to be dispersed or solubilized in a solvent, does not cause separation or aggregation of the carbon nanotubes even during long-term storage, has superior electrical conductivity, film formability and moldability, can be easily coated or covered onto a base material, and the resulting coated film has superior moisture resistance, weather resistance and hardness; a composite having a coated film composed thereof; and, their production methods. In order to achieve this object, the present invention provides a carbon nanotube composition that contains a conducting polymer (a) or heterocyclic compound trimer (i), a solvent (b) and carbon nanotubes (c), and may additionally contain a high molecular weight compound (d), a basic compound (e), a surfactant (f), a silane coupling agent (g) and colloidal silica (h) as necessary; a composite having a coated film composed of the composition; and, their production methods.

  本发明的目的是提供一种碳纳米管组合物，不会影响碳纳米管本身的特性，使碳纳米管可以分散或溶解在溶剂中，在长期储存期间不会导致碳纳米管分离或聚集，具有优异的电导性、成膜性和成型性，可以轻松地涂覆或覆盖在基材上，所得到的涂层膜具有优异的防潮性、耐候性和硬度；一种由涂层膜组成的复合材料；以及它们的生产方法。为了实现这一目的，本发明提供了一种碳纳米管组合物，其中包含导电聚合物(a)或杂环化合物三聚体(i)、溶剂(b)和碳纳米管(c)，并可根据需要另外包含高分子量化合物(d)、碱性化合物(e)、表面活性剂(f)、硅烷偶联剂(g)和胶体二氧化硅(h)；一种由该组合物组成的涂层膜复合材料；以及它们的生产方法。
• Carbon Nanotube Composition, Composite Having a Coated Film Composed of the Same, and Their Production Methods
  申请人：SAITOH Takashi

  公开号：US20090321688A1

  公开（公告）日：2009-12-31

  The object of the present invention is to provide a carbon nanotube composition that does not impair the characteristics of the carbon nanotubes itself, allows the carbon nanotubes to be dispersed or solubilized in a solvent, does not cause separation or aggregation of the carbon nanotubes even during long-term storage, has superior electrical conductivity, film formability and moldability, can be easily coated or covered onto a base material, and the resulting coated film has superior moisture resistance, weather resistance and hardness; a composite having a coated film composed thereof; and, their production methods. In order to achieve this object, the present invention provides a carbon nanotube composition that contains a conducting polymer (a) or heterocyclic compound trimer (i), a solvent (b) and carbon nanotubes (c), and may additionally contain a high molecular weight compound (d), a basic compound (e), a surfactant (f), a silane coupling agent (g) and colloidal silica (h) as necessary; a composite having a coated film composed of the composition; and, their production methods.

  本发明的目的是提供一种碳纳米管组合物，不会损害碳纳米管本身的特性，可以使碳纳米管分散或溶解于溶剂中，在长期存储期间不会导致碳纳米管分离或聚集，具有优异的电导率、膜成形性和成型性，可以轻松涂覆或覆盖在基材料上，并且所得到的涂层膜具有优异的防潮性、耐候性和硬度；一种由该组合物组成的涂层膜复合材料；以及它们的生产方法。为了实现这一目的，本发明提供了一种碳纳米管组合物，它包含导电聚合物(a)或杂环化合物三聚体(i)、溶剂(b)和碳纳米管(c)，并可以根据需要另外包含高分子化合物(d)、碱性化合物(e)、表面活性剂(f)、硅烷偶联剂(g)和胶体二氧化硅(h)；一种由该组合物组成的涂层膜复合材料；以及它们的生产方法。
• Process for production of heteroaryl-type boron compounds with iridium catalyst
  申请人：Miyaura Norio

  公开号：US20050148775A1

  公开（公告）日：2005-07-07

  The present invention provides an economically and industrially superior simple process that enables the selective production of an aromatic heterocyclic monoboron compound and aromatic heterocyclic diboron compound at a satisfactory yield and in a desired ratio by reacting an aromatic heterocyclic compound and a boron compound in a single step under mild conditions while changing only the charged ratios of the raw materials. The present invention provides a production process of a heteroaryl mono- or diboron compound comprising an aromatic heterocyclic compound and a boron compound in the form of bis(pinacolate)diboron or pinacolate diborane in the presence of a iridium-containing catalyst and a ligand such as a bipyridyl ligand.

  本发明提供了一种经济上和工业上优越的简单工艺，通过在温和条件下使芳香杂环化合物和硼化合物进行单步反应，同时仅改变原料的带电比例，就能以满意的产率和所需的比例选择性地生产芳香杂环单硼化合物和芳香杂环二硼化合物。本发明提供了一种杂芳基单硼或二硼化合物的生产工艺，该工艺由芳香杂环化合物和双(频哪醇)二硼或频哪醇二硼烷形式的硼化合物在含铱催化剂和配体如双吡啶配体的存在下组成。

表征谱图