retinylidenylprolinium carboxylate | 94476-70-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: retinylidenylprolinium carboxylate
• CAS: 94476-70-7
• 化学式: C₂₅H₃₅NO₂
• 分子量: 381.558
• InChiKey: QMVUHPVWOYCHBZ-BFZPFOOLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.51
• 重原子数：
  28.0
• 可旋转键数：
  6.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.52
• 拓扑面积：
  43.14
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  retinylidenylprolinium carboxylate 在 三乙胺 作用下， 以 乙醇 为溶剂， 生成 all-trans-retinal dimer
  参考文献：
  名称：

  The proline and β-lactoglobulin mediated asymmetric self-condensation of β-ionylideneacetaldehyde, retinal and related compounds.

  摘要：

  Proline was found to effectively mediate the asymmetric reaction of beta-ionylideneacetaldehyde 1A, retinal and related alpha,beta-unsaturated aldehydes to form their corresponding self-condensation products in reasonable enantiomeric excess (up to 65% ee). This same interesting conversion was also observed when 1A was incubated in the presence of the milk whey protein beta-lactoglobulin (BLG).

  DOI：

  10.1016/s0040-4039(00)79825-x
• 作为产物：
  描述：

  视黄醛 在 DL-脯氨酸 作用下， 以 乙醇 为溶剂， 生成 retinylidenylprolinium carboxylate
  参考文献：
  名称：

  The proline and β-lactoglobulin mediated asymmetric self-condensation of β-ionylideneacetaldehyde, retinal and related compounds.

  摘要：

  Proline was found to effectively mediate the asymmetric reaction of beta-ionylideneacetaldehyde 1A, retinal and related alpha,beta-unsaturated aldehydes to form their corresponding self-condensation products in reasonable enantiomeric excess (up to 65% ee). This same interesting conversion was also observed when 1A was incubated in the presence of the milk whey protein beta-lactoglobulin (BLG).

  DOI：

  10.1016/s0040-4039(00)79825-x