| 1423987-93-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1423987-93-2
• 化学式: C₂₈H₄₁NO₁₈
• 分子量: 679.629
• InChiKey: OKPHXJWCJRFFDH-QACPWNKNSA-N

反应信息

• 作为反应物：
  描述：

  在 三甲基氯硅烷 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 1.0h， 以83%的产率得到2,3,6-tri-O-acetyl-4-O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-D-glucopyranose
  参考文献：
  名称：

  A New Method for Selective Deprotection of AnomericN,O-Dimethylhydroxylamine Promoted by TMSCl

  摘要：

  TMSCl was shown to be an efficient reagent for selective deprotection of the anomeric position protected as N, O-dimethylhydroxylamine glycoside. This deprotection condition was proved to be compatible with a number of protecting groups, such as the TB-DPS, acetyl, benzyl, benzylidene, and benzoyl groups.

  DOI：

  10.1080/07328303.2012.762104
• 作为产物：
  描述：

  2,3,6-tri-O-acetyl-4-O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-D-glucopyranose 、 二甲羟胺盐酸盐 在 sodium acetate 作用下， 以 水 为溶剂， 反应 20.0h， 生成
  参考文献：
  名称：

  A New Method for Selective Deprotection of AnomericN,O-Dimethylhydroxylamine Promoted by TMSCl

  摘要：

  TMSCl was shown to be an efficient reagent for selective deprotection of the anomeric position protected as N, O-dimethylhydroxylamine glycoside. This deprotection condition was proved to be compatible with a number of protecting groups, such as the TB-DPS, acetyl, benzyl, benzylidene, and benzoyl groups.

  DOI：

  10.1080/07328303.2012.762104