5-norbornene-2-spiro-α-cyclohexanone-α'-spiro-2"-5"-norbornene | 1325717-00-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-norbornene-2-spiro-α-cyclohexanone-α'-spiro-2"-5"-norbornene
• 英文别名: 5-norbornene-2-spiro-α-cyclohexanone-α'-spiro-2''-5''-norbornene；5-norbornene-2-spiro-2'-cyclohexanone-6'-spiro-2''-5''-norbornene
• CAS: 1325717-00-7
• 化学式: C₁₈H₂₂O
• 分子量: 254.372
• InChiKey: KOLDCHLSVTVDAX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.72
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  甲醇 、 一氧化碳 、 5-norbornene-2-spiro-α-cyclohexanone-α'-spiro-2"-5"-norbornene 在 copper dichloride 、 palladium dichloride 作用下， 25.0 ℃ 、0.1 Pa 条件下， 反应 1.0h， 以99%的产率得到norbornane-2-spiro-α-cyclohexanone-α'-spiro-2"-norbornane-5,5",6,6"-tetracarboxylic acid tetramethyl ester
  参考文献：
  名称：

  Norbornane-2-spiro-α-cycloalkanone-α′-spiro-2″-norbornane-5,5″,6,6″-tetracarboxylic dianhydride, norbornane-2-spiro-α-cycloalkanone-α′-spiro-2″-norbornane-5,5″,6,6″-tetracarboxylic acid and ester thereof, method for producing norbornane-2-spiro-α-cycloalkanone-α′-spiro-2″-norbornane-5,5″,6,6″-tetracarboxylic dianhydride, polyimide obtained by using the same, and method for producing polyimide

  摘要：

  一个由以下一般公式（1）表示的诺博尔烷-2-螺-α-环戊酮-α′-螺-2″-诺博尔烷-5,5″,6,6″-四羧酐，其中在公式（1）中，n代表0到12的整数，R1s，R2，R3分别代表氢原子或类似物。

  公开号：

  US09456495B2
• 作为产物：
  描述：

  环己酮 在 盐酸 、 二甲胺 作用下， 以 乙二醇甲醚 、 水 为溶剂， 反应 5.5h， 生成 5-norbornene-2-spiro-α-cyclohexanone-α'-spiro-2"-5"-norbornene
  参考文献：
  名称：

  NORBORNANE-2-SPIRO- A-CYCLOALKANONE-A '-SPIRO-2''-NORBORNANE-5,5'',6,6''-TETRACARBOXYLIC DIANHYDRIDE, NORBORNANE-2-SPIRO- A-CYCLOALKANONE-A '-SPIRO-2''-NORBORNANE-5,5'',6,6''-TETRACARBOXYLIC ACID AND ESTER THEREOF, METHOD FOR PRODUCING NORBORNANE-2-SPIRO- A-CYCLOALKANONE-A '-SPIRO-2''-NORBORNANE-5,5'',6,6''-TETRACARBOXYLIC DIANHYDRIDE, POLYIMIDE OBTAINED USING SAME, AND METHOD FOR PRODUCING POLYIMIDE

  摘要：

  公开号：

  EP2535341B1

文献信息

• 5-NORBORNENE-2-SPIRO-a-CYCLOALKANONE-a'-SPIRO-2''-5''-NORBORNENE AND METHOD FOR PRODUCING THE SAME
  申请人：Komatsu Shinichi

  公开号：US20120310013A1

  公开（公告）日：2012-12-06

  A 5-norbornene-2-spiro-α-cycloalkanone-α′-spiro-2″-5″-norbornene represented by the following general formula (1): [in the formula (1), R 1 s, R 2 , and R 3 each independently represent a hydrogen atom or the like, and n represents an integer of 0 to 12].

  以下是通式（1）所代表的5-去氢-2-螺-α-环烷酮-α′-螺-2″-5″-去氢螺烯：[在通式（1）中，R1s，R2和R3分别独立地表示氢原子或类似物，n表示0至12的整数]。
• METHOD FOR PRODUCING ESTER COMPOUND
  申请人：JX NIPPON OIL & ENERGY CORPORATION

  公开号：US20160102044A1

  公开（公告）日：2016-04-14

  A method for producing an ester compound including reacting a compound having at least one cyclic structure of a norbornene ring and a norbornadiene ring with an alcohol and carbon monoxide by using a palladium catalyst and an oxidizing agent, to thereby introduce ester groups to carbon atoms forming a double bond in the cyclic structure and obtain the ester compound, wherein the palladium catalyst comprises a palladium complex having a bipyridyl as a ligand.

  一种制备酯化合物的方法，包括使用钯催化剂和氧化剂，将至少具有一个环状结构的诺博尔烯环和诺博尔二烯环化合物与醇和一氧化碳反应，从而将酯基引入环状结构中形成双键的碳原子，并获得酯化合物，其中钯催化剂包括以联吡啶为配体的钯配合物。
• METHOD FOR PRODUCING ESTER COMPOUND AND PALLADIUM CATALYST USED IN THE METHOD
  申请人：JX Nippon Oil & Energy Corporation

  公开号：US20150343432A1

  公开（公告）日：2015-12-03

  A method for producing an ester compound includes reacting a compound having at least one cyclic structure of a norbornene ring and a norbornadiene ring with an alcohol and carbon monoxide by using a palladium catalyst and an oxidizing agent, to thereby introduce ester groups to carbon atoms forming a double bond in the cyclic structure and obtaining the ester compound, wherein the palladium catalyst includes a palladium acetate having a nitrite ligand in an amount of 10% by mole or more in terms of metal, and the palladium acetate having a nitrite ligand is represented by the general formula (1): Pd 3 (CH 3 COO) 5 (NO 2 ).

  一种制备酯类化合物的方法，包括使用钯催化剂和氧化剂，通过将至少具有一个环状结构的诺博尔烯环和诺博尔二烯环化合物与醇和一氧化碳反应，从而将酯基引入到环状结构中形成双键的碳原子中，并获得酯类化合物，其中钯催化剂包括具有硝基配体的乙酸钯，其金属量为摩尔数的10％或更多，乙酸钯的硝基配体由通式（1）表示：Pd3（CH3COO）5（NO2）。
• NORBORNANE-2-SPIRO-alpha-CYCLOALKANONE-alpha'-SPIRO-2''-NORBORNANE-5,5'',6,6''-TETRACARBOXYLIC DIANHYDRIDE, NORBORNANE-2-SPIRO-alpha-CYCLOALKANONE-alpha'-SPIRO-2''-NORBORNANE-5,5'',6,6''-TETRACARBOXYLIC ACID AND ESTER THEREOF, METHOD FOR PRODUCING NORBORNANE-2-SPIRO-alpha-CYCLOALKANONE-alpha'-SPIRO-2''-NORBORNANE-5,5'',6,6''-TETRACARBOXYLIC DIANHYDRIDE, POLYIMIDE OBTAINED BY USING THE SAME, AND METHOD FOR PRODUCING POLYIMIDE
  申请人：Matsumoto Toshihiko

  公开号：US20130079490A1

  公开（公告）日：2013-03-28

  A norbornane-2-spiro-α-cycloalkanone-α′-spiro-2″-norbornane-5,5″,6,6″-tetracarboxylic dianhydride represented by the following general formula (1): [in the formula (1), n represents an integer of 0 to 12, and R 1 s, R 2 , R 3 each independently represents a hydrogen atom or the like].
• NORBORNANE-2-SPIRO-a-CYCLOALKANONE-a'-SPIRO-2"-NORBORNANE-5,5",6,6"-TETRACARBOXYLIC DIANHYDRIDE, NORBORNANE-2-SPIRO-a- CYCLOALKANONE-a'-SPIRO-2"-NORBORNANE-5,5",6,6"-TETRACARBOXYLIC ACID AND ESTER THEREOF, METHOD FOR PRODUCING NORBORNANE-2-SPIRO-a-CYCLOALKANONE-a'-SPIRO-2"-NORBORNANE-5,5",6,6"-TETRACARBOXYLIC DIANHYDRIDE, POLYIMIDE OBTAINED BY USING THE SAME, AND METHOD FOR PRODUCING POLYIMIDE
  申请人：MATSUMOTO Toshihiko

  公开号：US20150086753A1

  公开（公告）日：2015-03-26

  A norbornane-2-spiro-α-cycloalkanone-α′-spiro-2″-norbornane-5,5″,6,6″-tetracarboxylic dianhydride represented by the following general formula (1): wherein the formula (1), n represents an integer of 0 to 12, and R 1 s, R 2 , R 3 each independently represents a hydrogen atom or the like.