8-hydroxy-quinoline-5-carboxylic acid ; hydrochloride | 878779-63-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 8-hydroxy-quinoline-5-carboxylic acid ; hydrochloride
• 英文别名: 8-Hydroxy-chinolin-5-carbonsaeure; Hydrochlorid；8-Hydroxyquinoline-5-carboxylic acid hydrochloride；8-hydroxyquinoline-5-carboxylic acid;hydrochloride
• CAS: 878779-63-6
• 化学式: C₁₀H₇NO₃*ClH
• 分子量: 225.631
• InChiKey: CJEGNFIRKBIXTL-UHFFFAOYSA-N

物化性质

• 熔点：
  239 °C (decomp)

计算性质

• 辛醇/水分配系数(LogP)：
  2.06
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  70.4
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  sodium hydroxide 、 dichlorobis(dimethyl sulfoxide)platinum(II) 、 8-hydroxy-quinoline-5-carboxylic acid ; hydrochloride 以 甲醇 、 丙酮 为溶剂， 反应 24.0h， 以78%的产率得到
  参考文献：
  名称：

  Size-selective mesoporous silica-based Pt(II) complex as efficient and reusable photocatalytic material

  摘要：

  The grafting of a Pt(II) photocatalyst into three different mesoporous silica-based materials with different particle sizes and pore sizes was easily achieved through an amide bond formation. The analysis and results of the different characterization techniques showed that the catalyst is immobilized inside the pores of the materials and the photophysical properties of the catalyst are preserved after the covalent anchoring. The photocatalytic material catalyzed efficiently the debromination reaction of different substrates and is reused without detriment in its catalytic activity. In addition, the incorporation of the catalyst into mesoporous silica materials with different pore size allows the selective debromination of substrates by size discrimination. (C) 2019 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jcat.2019.04.015