1,6-bis(8-hydroxyquinolin-5-yl)-2,5-dioxahexane | 367927-60-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 1,6-bis(8-hydroxyquinolin-5-yl)-2,5-dioxahexane
• CAS: 367927-60-4
• 化学式: C₂₂H₂₀N₂O₄
• 分子量: 376.412
• InChiKey: LPIQXFKZGLVTJS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.93
• 重原子数：
  28.0
• 可旋转键数：
  7.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  84.7
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  1,6-bis(8-hydroxyquinolin-5-yl)-2,5-dioxahexane 、 manganese(II) acetate 在 aq. NH₃ 作用下， 以 甲酸 为溶剂， 以85%的产率得到[1,6-bis(8-oxyquinolin-5-yl)-2,5-dioxahexano]diaquomanganese(II)
  参考文献：
  名称：

  COORDINATION POLYMERS OF 1,6-BIS(8-HYDROXYQUINOLIN-5-YL)-2,5-DIOXAHEXANE

  摘要：

  Coordination polymers of a novel bis(oxine) bidentate ligand namely 1,6-bis(8-hydroxyquinolin-5-yl)-2.5-dioxahexane (H2L) have been prepared with the metal ions Zn(II). Cu(II), Ni(II), Co(II) and Mn(II). The novel bis(bidentate) ligand (H2L) was synthesized by condensation of 5-chloromethyl-8-hydroxyquinoline hydrochloride with ethylene glycol in the presence of a base catalyst. All of these coordination polymers and the parent ligand were characterized by elemental analyses, IR spectral and diffuse reflectance spectral studies. The thermal stability and number-average molecular weights ((M) over bar (n)) of all of the coordination polymers were determined by thermogravimetric analyses and non-aqueous conductometric titrations, respectively. Besides this, all of the coordination polymers also have been characterized by their magnetic susceptibilities.

  DOI：

  10.1081/sim-100104793