Ce(8-hydroxyquinolinate)₄ | 51772-50-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: Ce(8-hydroxyquinolinate)₄
• 英文别名: [Ce(8-hydroxyquinoline)4]；Ce(OQ)₄
• CAS: 51772-50-0
• 化学式: C₃₆H₂₄CeN₄O₄
• 分子量: 716.731
• InChiKey: YLBLSIFSSJCCJD-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  8-羟基喹啉 、 cerium(IV) sulfate tetrahydrate 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 以74.2%的产率得到Ce(8-hydroxyquinolinate)₄
  参考文献：
  名称：

  Synthesis and crystal structures of cerium(IV) complexes with 8-quinolinolate and amine bis(phenolate) ligands

  摘要：

  Two cerium(IV) complexes of Ce(OQ)(4) (1) (HOQ = 8-hydroxyquinoline) and Ce(L)(2)center dot DME (2 center dot DME) (LH2 = Me2NCH2CH2CH2N{CH2-(3,5-Bu-t(2)-C6H2-2-OH)}(2)) have been synthesized and characterized by elemental analysis, infrared spectra and X-ray crystallography. Complex 1 is a new type of homoleptic 8-quinolinolate lanthanide complex and its overall geometry is like a four-wing-waterwheel. Complex 2 has two tridentate (ONO) amine bis(phenolate) ligands with their terminal N atoms in side-arms without participating in coordination. Both of 1 and 2 can catalyze the oxidation of benzyl alcohol. The conversion of benzyl alcohol by 2 is higher than that by 1 under comparable conditions. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.11.020
• 作为试剂：
  描述：

  苯甲醇 在 sodium bromate 、 Ce(8-hydroxyquinolinate)₄ 作用下， 生成 苯甲醛 、 苯甲酸
  参考文献：
  名称：

  Synthesis and crystal structures of cerium(IV) complexes with 8-quinolinolate and amine bis(phenolate) ligands

  摘要：

  Two cerium(IV) complexes of Ce(OQ)(4) (1) (HOQ = 8-hydroxyquinoline) and Ce(L)(2)center dot DME (2 center dot DME) (LH2 = Me2NCH2CH2CH2N{CH2-(3,5-Bu-t(2)-C6H2-2-OH)}(2)) have been synthesized and characterized by elemental analysis, infrared spectra and X-ray crystallography. Complex 1 is a new type of homoleptic 8-quinolinolate lanthanide complex and its overall geometry is like a four-wing-waterwheel. Complex 2 has two tridentate (ONO) amine bis(phenolate) ligands with their terminal N atoms in side-arms without participating in coordination. Both of 1 and 2 can catalyze the oxidation of benzyl alcohol. The conversion of benzyl alcohol by 2 is higher than that by 1 under comparable conditions. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.11.020