[Ru(η⁶-p-cymene)Cl₂(N,N-dimethylpyridin-4-amine)] | 423120-00-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: [Ru(η⁶-p-cymene)Cl₂(N,N-dimethylpyridin-4-amine)]
• 英文别名: p-dimethylaminopyridine(p-cymene)dichlororuthenium(II)；N,N-dimethylpyridin-4-amine;1-methyl-4-propan-2-ylbenzene;ruthenium(2+);dichloride
• CAS: 423120-00-7
• 化学式: C₁₇H₂₄Cl₂N₂Ru
• 分子量: 428.367
• InChiKey: KGLLLHJMBFHBKJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.73
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  16.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  马来酸酐 、 [Ru(η⁶-p-cymene)Cl₂(N,N-dimethylpyridin-4-amine)] 以 甲苯 为溶剂， 以76%的产率得到4-maleimidopyridyl(p-cymene)dichlororuthenium(II)
  参考文献：
  名称：

  Syntheses and catalytic properties of alternating copolymers of poly[4-maleimidopyridyl(p-cymene)dichloro Ru(II)] with γ-methacryloxypropyl trimethoxysilane

  摘要：

  A new monomer, 4-maleimidopyridyl(p-cymene)dichloro Ru(II), was synthesized by the reaction of maleic anhyride with p-dimethylaminopyridine(p-cymene)dichloro ruthenium(II). The homopolymer ofmaleimidopyridyl(p-cymene)dichloro Ru(II) and its copolymers with gamma-methacryloxypropyl trimethoxysilane were prepared by radical polymerization with benzoyl peroxide as an initiator at 75 degreesC. The structures of the synthesized monomer and polymers were identified by Fourier transform infrared, H-1 NMR, and C-13 NMR spectroscopies. Thermal behavior of the polymers were determined by differential thermal analysis, and thermogravimetric analysis, glass transition temperature was determined by differential scanning calorimeter.Excellent selectivities were observed by using Ru (II) complex as the catalyst in hydrosilylation reactions. The heterogeneous Ru(II) catalyst can also be recyled and reused without significant loss of selectivity or activity. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(01)00392-2
• 作为产物：
  描述：

  4-二甲氨基吡啶 、 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 以 二氯甲烷 为溶剂， 以70%的产率得到[Ru(η⁶-p-cymene)Cl₂(N,N-dimethylpyridin-4-amine)]
  参考文献：
  名称：

  作为 N-烷基化催化剂的卤化钌配合物

  摘要：

  制备了一系列具有氯化物、溴化物或碘化物配体的钌 - 芳烃化合物，并将其作为叔丁胺与苯乙醇的均相氧化还原中性烷基化的催化剂进行测试，并与先前报道的催化剂 [RuCl2(p-cymene)]2 进行比较, 在二膦 1,1'-双（二苯基膦基）二茂铁 (dppf) 的存在下。使用碘化钌化合物获得最佳催化活性。研究了 [RuX(p-cymene)(dppf)][X] 或 [(RuX2(p-cymene)) 2(dppf)]（X = 卤化物）在所用催化条件下的形成。

  DOI：

  10.1002/ejic.201400117

文献信息

• Ruthenium-catalysed multicomponent synthesis of borasiloxanes
  作者：Basujit Chatterjee、Chidambaram Gunanathan

  DOI：10.1039/c7cc00787f

  日期：——

  We present the selective atom economical synthesis of borasiloxanes using a multi-component approach directly from the one-pot ruthenium catalysed reaction of boranes, silanes and water

  我们提出了直接从一锅钌催化的硼烷，硅烷和水的多组分方法直接使用多组分方法经济地合成硼烷硅氧烷的方法